Spin crossover in iron (III) complexes

DJ Harding, P Harding, W Phonsri - Coordination Chemistry Reviews, 2016 - Elsevier
Spin crossover compounds are a diverse class of switchable materials with applications
ranging from data storage devices to sensors. Iron (III) spin crossover complexes have …

Polymorphism in spin-crossover systems

J Tao, RJ Wei, RB Huang, LS Zheng - Chemical Society Reviews, 2012 - pubs.rsc.org
The occurrence of spin-crossover (SCO) highly depends on external influences, ie
temperature, pressure, light irradiation or magnetic field, this electronic switching …

Study on boron and fluorine-doped C3N4 as a solid activator for cyclohexane oxidation with H2O2 catalyzed by 8-quinolinolato ironIII complexes under visible light …

S Tang, Z Fu, Y Li, Y Li - Applied Catalysis A: General, 2020 - Elsevier
This paper discloses that boron and fluorine-doped carbon nitride (C 3 N 4 BF), as a solid
activator, can efficiently accelerate the relatively inert 5, 7-dichloro-8-quinolinolato iron (III) …

Iron Spin-Crossover compounds: from fundamental studies to practical applications

P Gamez, JS Costa, M Quesada, G Aromí - Dalton Transactions, 2009 - pubs.rsc.org
Over the past five years, the spin-crossover (SCO) phenomenon has experienced a clear
new lease of interest from the scientific community coinciding with the recent publication of …

[HTML][HTML] Symmetry breaking in iron (II) spin-crossover molecular crystals

N Ortega-Villar, MC Muñoz, JA Real - Magnetochemistry, 2016 - mdpi.com
This review provides an up to date survey of a singular class of iron (II) spin crossover (SCO)
molecular materials that undergo high-spin (HS)↔ low-spin (LS) phase transitions …

A Symmetry‐Breaking Spin‐State Transition in Iron (III)

M Griffin, S Shakespeare, HJ Shepherd… - Angewandte Chemie …, 2011 - Wiley Online Library
Molecular spin crossover (SCO) has been intensively studied over the last 20 years,
motivated both by the need to develop improved understanding of the phenomenon and in …

Spin‐State Ordering on One Sub‐lattice of a Mononuclear Iron (III) Spin Crossover Complex Exhibiting LIESST and TIESST

KD Murnaghan, C Carbonera, L Toupet… - … A European Journal, 2014 - Wiley Online Library
The two‐step spin crossover in mononuclear iron (III) complex [Fe (salpm) 2] ClO4⋅ 0.5
EtOH (1) is shown to be accompanied by a structural phase transition as concluded from …

Cycloheptyl-fused iminopyridine-iron catalysts for isoprene polymerization with enhanced activity and thermal stability

R Yuan, G Ren, Q Mahmood, Y Zeng, Y Wang… - …, 2023 - ACS Publications
In this study, a set of six cycloheptyl-fused iminopyridine-ligated iron complexes were
prepared and investigated for isoprene polymerization under various reaction conditions …

Abrupt two-step and symmetry breaking spin crossover in an iron (III) complex: an exceptionally wide [LS–HS] plateau

DJ Harding, W Phonsri, P Harding, KS Murray… - Dalton …, 2015 - pubs.rsc.org
Abrupt two-step and symmetry breaking spin crossover in an iron( iii ) complex: an
exceptionally wide [LS–HS] plateau - Dalton Transactions (RSC Publishing) DOI:10.1039/C4DT03184A …

An unusual discontinuity in the thermal spin transition in [Co (terpy) 2][BF 4] 2

CA Kilner, MA Halcrow - Dalton Transactions, 2010 - pubs.rsc.org
Single crystal and powder samples of [Co (terpy) 2][BF4] 2 are low spin below 100 K but
show a typically gradual thermal spin-transition on warming, centred near 270 K. However …