Boron: its role in energy‐related processes and applications

Z Huang, S Wang, RD Dewhurst… - Angewandte Chemie …, 2020 - Wiley Online Library
Boron's unique position in the Periodic Table, that is, at the apex of the line separating
metals and nonmetals, makes it highly versatile in chemical reactions and applications …

Three‐and four‐coordinate, boron‐based, thermally activated delayed fluorescent emitters

SS Kothavale, JY Lee - Advanced Optical Materials, 2020 - Wiley Online Library
Recent developments in purely organic‐material‐based thermally activated delayed
fluorescence (TADF) emitters are helping to make them suitable for commercial applications …

Brighten triplet excitons of carbon nanodots for multicolor phosphorescence films

Q Cao, KK Liu, YC Liang, SY Song, Y Deng, X Mao… - Nano Letters, 2022 - ACS Publications
Triplet excitons usually do not emit light under ambient conditions due to the spin-forbidden
transition rule, thus they are called dark excitons. Herein, triplet excitons in carbon nanodots …

Recent advances in azaborine chemistry

PG Campbell, AJV Marwitz… - Angewandte Chemie …, 2012 - Wiley Online Library
The chemistry of organoboron compounds has been primarily dominated by their use as
powerful reagents in synthetic organic chemistry. Recently, the incorporation of boron as …

Developing Conjugated Polymers with High Electron Affinity by Replacing a CC Unit with a BN Unit

C Dou, Z Ding, Z Zhang, Z Xie, J Liu… - Angewandte Chemie …, 2015 - Wiley Online Library
The key parameters of conjugated polymers are lowest unoccupied molecular orbital
(LUMO) and highest occupied molecular orbital (HOMO) energy levels. Few approaches …

Planarized triarylboranes: stabilization by structural constraint and their plane-to-bowl conversion

Z Zhou, A Wakamiya, T Kushida… - Journal of the American …, 2012 - ACS Publications
Triphenylborane and 9, 10-diphenyl-9, 10-dihydro-9, 10-diboraanthracene, constrained to a
planar arrangement with methylene tethers, were synthesized by intramolecular multi-fold …

[HTML][HTML] (Hetero) arene-fused boroles: a broad spectrum of applications

J He, F Rauch, M Finze, TB Marder - Chemical Science, 2021 - pubs.rsc.org
(Hetero) arene-fused boroles are a class of compounds containing a 5-membered boron
diene-ring. Based on their molecular framework, the (hetero) arene-fused boroles can be …

Highly Efficient Blue Phosphorescence from Triarylboron-Functionalized Platinum(II) Complexes of N-Heterocyclic Carbenes

ZM Hudson, C Sun, MG Helander… - Journal of the …, 2012 - ACS Publications
The first examples of BMes2-functionalized NHC chelate ligands have been achieved. Their
Pt (II) acetylacetonate complexes have been synthesized and fully characterized. These …

Polycyclic π-electron system with boron at its center

S Saito, K Matsuo, S Yamaguchi - Journal of the American …, 2012 - ACS Publications
We disclose a new planarized triarylborane in which the tri-coordinated boron atom is
embedded in a fully fused polycyclic π-conjugated skeleton. The compound shows high …

Applications of triarylborane materials in cell imaging and sensing of bio-relevant molecules such as DNA, RNA, and proteins

SM Berger, TB Marder - Materials Horizons, 2022 - pubs.rsc.org
Triarylboranes have been known for more than 100 years and have found potential
applications in various fields such as anion sensors and optoelectronics, for example in …