Solar‐to‐H2O2 Catalyzed by Covalent Organic Frameworks

Z Yong, T Ma - Angewandte Chemie, 2023 - Wiley Online Library
Benefiting from the excellent structural tunability, robust framework, ultrahigh porosity, and
rich active sites, covalent organic frameworks (COFs) are widely recognized as promising …

Covalent organic frameworks for energy conversion in photocatalysis

T He, Y Zhao - Angewandte Chemie International Edition, 2023 - Wiley Online Library
Intensifying energy crises and severe environmental issues have led to the discovery of
renewable energy sources, sustainable energy conversion, and storage technologies …

Dual donor-acceptor covalent organic frameworks for hydrogen peroxide photosynthesis

C Qin, X Wu, L Tang, X Chen, M Li, Y Mou, B Su… - Nature …, 2023 - nature.com
Constructing photocatalytically active and stable covalent organic frameworks containing
both oxidative and reductive reaction centers remain a challenge. In this study …

Tuning excited state electronic structure and charge transport in covalent organic frameworks for enhanced photocatalytic performance

Z Chen, J Wang, M Hao, Y Xie, X Liu, H Yang… - Nature …, 2023 - nature.com
Covalent organic frameworks (COFs) represent an emerging class of organic photocatalysts.
However, their complicated structures lead to indeterminacy about photocatalytic active sites …

Covalent organic frameworks for direct photosynthesis of hydrogen peroxide from water, air and sunlight

F Liu, P Zhou, Y Hou, H Tan, Y Liang, J Liang… - Nature …, 2023 - nature.com
Solar-driven photosynthesis is a sustainable process for the production of hydrogen
peroxide, the efficiency of which is plagued by side reactions. Metal-free covalent organic …

Tuning local charge distribution in multicomponent covalent organic frameworks for dramatically enhanced photocatalytic uranium extraction

H Yang, M Hao, Y Xie, X Liu, Y Liu… - Angewandte Chemie …, 2023 - Wiley Online Library
Optimizing the electronic structure of covalent organic framework (COF) photocatalysts is
essential for maximizing photocatalytic activity. Herein, we report an isoreticular family of …

Sulfone‐Modified Covalent Organic Frameworks Enabling Efficient Photocatalytic Hydrogen Peroxide Generation via One‐Step Two‐Electron O2 Reduction

Y Luo, B Zhang, C Liu, D Xia, X Ou… - Angewandte Chemie …, 2023 - Wiley Online Library
Photocatalytic oxygen reduction reaction (ORR) offers a promising hydrogen peroxide
(H2O2) synthetic strategy, especially the one‐step two‐electron (2e−) ORR route holds great …

Piperazine-Linked Metalphthalocyanine Frameworks for Highly Efficient Visible-Light-Driven H2O2 Photosynthesis

Q Zhi, W Liu, R Jiang, X Zhan, Y Jin… - Journal of the …, 2022 - ACS Publications
Artificial photosynthesis of H2O2 from O2 reduction provides an energy-saving, safe, and
green approach. However, it is still critical to develop highly active and selective 2e–oxygen …

Oxidation‐Reduction Molecular Junction Covalent Organic Frameworks for Full Reaction Photosynthesis of H2O2

JN Chang, Q Li, JW Shi, M Zhang, L Zhang… - Angewandte …, 2023 - Wiley Online Library
The full reaction photosynthesis of H2O2 that can combine water‐oxidation and oxygen‐
reduction without sacrificial agents is highly demanded to maximize the light‐utilization and …

Covalent Organic Frameworks Containing Dual O2 Reduction Centers for Overall Photosynthetic Hydrogen Peroxide Production

D Chen, W Chen, Y Wu, L Wang, X Wu… - Angewandte Chemie …, 2023 - Wiley Online Library
Covalent organic frameworks (COFs) are highly desirable for achieving high‐efficiency
overall photosynthesis of hydrogen peroxide (H2O2) via molecular design. However …