A review on the Pd-based three-way catalyst

J Wang, H Chen, Z Hu, M Yao, Y Li - Catalysis Reviews, 2015 - Taylor & Francis
The application of Pd in three-way catalyst represents a significant technology breakthrough
for the removal of pollutants from gasoline powered vehicle exhaust gas. Pd shows superior …

Deactivation of Pd catalysts by water during low temperature methane oxidation relevant to natural gas vehicle converters

R Gholami, M Alyani, KJ Smith - Catalysts, 2015 - mdpi.com
Effects of H2O on the activity and deactivation of Pd catalysts used for the oxidation of
unburned CH4 present in the exhaust gas of natural-gas vehicles (NGVs) are reviewed …

CH4 Oxidation Activity in Pd and Pt–Pd Bimetallic Catalysts: Correlation with Surface PdOx Quantified from the DRIFTS Study

EJ Jang, J Lee, DG Oh, JH Kwak - ACS Catalysis, 2021 - ACS Publications
For Pd-based catalysts, facile and fast interconversion between Pd and PdO occurs
continuously during the CH4 oxidation reaction, which makes it challenging to determine …

Effect of metal-metal and metal-support interaction on activity and stability of Pd-Rh/alumina in CO oxidation

AA Vedyagin, AM Volodin, RM Kenzhin… - Catalysis Today, 2017 - Elsevier
A series of Pd-Rh/alumina catalysts with total precious metals loading of 0.2 wt.% was
prepared by means of mechanical mixing of monometallic precursors and incipient wetness …

Ostwald-ripening sintering kinetics of Pd-based three-way catalyst: Importance of initial particle size of Pd

SB Kang, JB Lim, D Jo, IS Nam, BK Cho… - Chemical Engineering …, 2017 - Elsevier
The sintering rates of commercial and lab-prepared Pd three-way catalysts (TWCs) as a
function of the catalyst mileage were examined by CO chemisorption, XRD and TEM …

Catalyst Deactivation via Rhodium–Support Interactions under High-Temperature Oxidizing Conditions: A Comparative Study on Hexaaluminates versus Al2O3

M Machida, Y Uchida, S Iwashita, H Yoshida… - ACS …, 2021 - ACS Publications
Undesired solid-state reactions between rhodium (Rh) oxide and γ-Al2O3 are a major cause
of catalyst deactivation under high-temperature-oxidizing atmosphere, given that the Rh3+ …

Insights into the role of Pt on Pd catalyst stabilized by magnesia-alumina spinel on gama-alumina for lean methane combustion: Enhancement of hydrothermal …

J Chen, Y Wu, W Hu, P Qu, X Liu, R Yuan, L Zhong… - Molecular …, 2020 - Elsevier
It is an urgent desire to decrease release of methane, a potential greenhouse gas, over
methane-oxidation catalysts. However, the commonly used Pd-based catalysts normally …

Thermal stability of Pd-containing LaAlO3 perovskite as a modern TWC

YJ Kim, JH Lim, BK Cho, SB Hong, IS Nam… - Journal of …, 2015 - Elsevier
TWC activity and thermal stability of LaAlO 3-based Pd catalysts were investigated under
simulated gasoline engine exhaust conditions. The LaAlO 3-based catalysts revealed a …

Pd model catalysts: Effect of air pulse length during redox aging on Pd redispersion

JA Lupescu, JW Schwank, GB Fisher, J Hangas… - Applied Catalysis B …, 2018 - Elsevier
Nano-sized noble metal particles are an essential component in automotive catalytic
converters. However, during customer in-use operation they agglomerate into larger …

Part I: A Comparative Thermal Aging Study on the Regenerability of Rh/Al2O3 and Rh/CexOy-ZrO2 as Model Catalysts for Automotive Three Way Catalysts

Q Zheng, R Farrauto, M Deeba, I Valsamakis - Catalysts, 2015 - mdpi.com
The rhodium (Rh) component in automotive three way catalysts (TWC) experiences severe
thermal deactivation during fuel shutoff, an engine mode (eg, at downhill coasting) used for …