(E)-β-Iodo vinylsulfones are synthesized under ultrasound irradiation using alkynes, sulfonyl
hydrazides, potassium iodide and hydrogen peroxide. The key features of this protocol are …

N, N'-Disulfonylhydrazines have been proven to be the most reactive precursors of the
sulfonyl radicals among all types of sulfonyl substituted hydrazines as early as half a century …

An efficient and convenient approach for the construction of various (E)-β-iodovinyl sulfones
has been developed through potassium persulfate/tetrabutylammonium iodide-facilitated …

The synthesis of a novel monomeric precursor and its butadiyne‐bridged dimeric form for
the preparation of novel π‐conjugated organophosphorus compounds is presented. The …

The π‐accepting property of alkene‐like phosphaethenes (–P= C<) is attractive for the
development of Lewis acidic transition‐metal catalysts. The stereoselective …

This account highlights the versatility of phosphanylphosphonates, which can be used for
the preparation of phosphorus-containing π-systems and as reagents for the reductive …

This account reviews some innovative (“non-classical”) synthetic strategies for the formation
of CP bonds developed during the last decades. It provides examples of the most important …

Polymers containing phosphorus, as well as their heavier analogs, display a large variety of
properties originating from the diverse bonding situations realized in these different …

Treatment of Mes* P= C (Si (CH3) 3) Br with CH2= CHMgBr in the presence of Pd (0) affords
1-phosphabutadiene Mes* P= C (Si (CH3) 3)–CH= CH2 (1) selectively as the Z isomer …

This article discusses polymers containing phosphorus centers that impart essential
properties, functions, and responses to the discussed materials. By incorporating this …