Presented herein is a comprehensive account of the electronic structure of corrole
derivatives. Our knowledge in this area derives from a broad range of methods, including UV …

This review covers the functionalization reactions of meso-arylcorroles, both at the inner
core, as well as the peripheral positions of the macrocycle. Experimental details for the …

The renaissance in corrole chemistry is strongly correlated with synthetic breakthroughs that
started in 1999, regarding the one-pot rather than multistep syntheses of this heme-like N4 …

Solid-state photochromic materials are very attractive due to their promising future in
advanced functional materials with reversible and tunable optical properties. However, the …

With the exception of a single accidental synthesis, rhenium corroles are unknown, but of
great interest as catalysts and potential radiopharmaceuticals. Oxidative metalation of meso …

Platinum has been inserted into corroles for the first time and three oxidized PtIV (corrole˙
2−) ArAr′ complexes have been structurally characterized. The Soret maxima of these …

This article presents a brief review of recent developments in metallocorrole chemistry, with
a focus on species with significant displacement of the metal from the N4 plane of the corrole …

The first 99Tc corroles have been synthesized and fully characterized. A single‐crystal X‐ray
structure of a 99TcO triarylcorrole revealed nearly identical geometry parameters as the …

The oxidative metalation method, involving the interaction of free‐base meso‐triarylcorroles
and W (CO) 6 in refluxing decalin, led to a set of three tungsten (VI) biscorroles, the first …

The first example of a diboryl corrole complex,[(BF2) 2 (Br8T (4-F–P) C)]−(Br8T (4-F–P) C=
trianion of 2, 3, 7, 8, 12, 13, 17, 18-octabromo-5, 10, 15-tris (4-fluorophenyl) corrole), has …