Conspectus Recently, alkene dicarbofunctionalization, ie, the powerful organic synthesis
method of alkene difunctionalization with two carbon sources, emerged as a formidable …

The catalytic dicarbofunctionalization of unsaturated π bonds represents a powerful platform
for the rapid construction of complex motifs. Despite remarkable progress, novel and efficient …

The cross-electrophile dialkylation of alkenes enables the formation of two C (sp3)–C (sp3)
bonds from readily available starting materials in a single transformation, thereby providing …

An asymmetric three-component carbosulfonylation of alkenes is presented here. The
reaction, involving the simultaneous formation of a C–C and a C–S bond across the π …

Selective construction of two distinct alkyl–alkyl bonds across the C= C bond of simple
unactivated olefins is a persistent challenge in organic synthesis. Transition metal-catalysed …

Difunctionalization of olefins offers an attractive approach to access complex chiral
structures. Reported herein is the design of N-protected O-allylhydroxyamines as …

The development of bimolecular homolytic substitution (SH2) catalysis has expanded cross-
coupling chemistries by enabling the selective combination of any primary radical with any …

1, 2-Dicarbofunctionalization of alkenes represents an appealing strategy for chemical bond
formation in organic synthesis, which could enable the rapid construction of molecular …

Transition-metal-catalyzed reductive coupling reactions have been considered as a
powerful tool to convert two electrophiles into value-added products. Numerous related …

The construction of C (sp 3)–C (sp 3) bonds remains one of the most difficult challenges in
cross-coupling chemistry. Here, we report a photoredox/nickel dual catalytic approach that …