Structure/reactivity relationships and mechanism from X-ray data and spectroscopic kinetic analysis
The development in crystallography is nothing short of phenomenal, showing an ever
increasing trend towards applications, such as in molecular biology.'Traditional'small …
increasing trend towards applications, such as in molecular biology.'Traditional'small …
Novel paste electrodes based on phosphonium salt room temperature ionic liquids for studying the redox properties of insoluble compounds
MN Khrizanforov, DM Arkhipova, RP Shekurov… - Journal of Solid State …, 2015 - Springer
A new carbon paste electrode is described, which contains the room temperature ionic liquid
(RTIL) tri (tert-butyl)(dodecyl) phosphonium tetrafluoroborate as binder. The advantages of …
(RTIL) tri (tert-butyl)(dodecyl) phosphonium tetrafluoroborate as binder. The advantages of …
Synthesis and Group Electronegativity Implications on the Electrochemical and Spectroscopic Properties of Diferrocenyl meso-Substituted Porphyrins
A Auger, JC Swarts - Organometallics, 2007 - ACS Publications
Two different condensations of appropriate dipyrromethanes and aldehydes resulted in two
structural isomers of metal-free, meso-substituted diferrocenyldipentafluorophenyl …
structural isomers of metal-free, meso-substituted diferrocenyldipentafluorophenyl …
Electrochemical and density functional theory modeled reduction of enolized 1, 3-diketones
A Kuhn, KG Von Eschwege, J Conradie - Electrochimica acta, 2011 - Elsevier
Cathodic peak potentials (E pc) of ten enolized 1, 3-substituted 1, 3-diketones, R 1 COCHC
(OH) R 2 derivatives containing electron withdrawing and/or electron donating groups, were …
(OH) R 2 derivatives containing electron withdrawing and/or electron donating groups, were …
Synthetic, electrochemical and structural aspects of a series of ferrocene-containing dicarbonyl β-diketonato rhodium (I) complexes
J Conradie, TS Cameron, MAS Aquino… - Inorganica chimica …, 2005 - Elsevier
Treatment of [Rh (β-diketonato)(cod)] with CO resulted in better yields of [Rh
(FcCOCHCOR)(CO) 2] than by treating [Rh (Cl)(CO) 2] 2 with FcCOCH2COR, R= CF3 …
(FcCOCHCOR)(CO) 2] than by treating [Rh (Cl)(CO) 2] 2 with FcCOCH2COR, R= CF3 …
Density functional theory calculations of Rh-β-diketonato complexes
J Conradie - Dalton Transactions, 2015 - pubs.rsc.org
Density functional theory (DFT) results on the geometry, energies and charges of selected
Rh-β-diketonato reactants, products and transition states are discussed. Various DFT …
Rh-β-diketonato reactants, products and transition states are discussed. Various DFT …
Cytotoxicity and cell death pathways invoked by two new rhodium-ferrocene complexes in benign and malignant prostatic cell lines
B Weber, A Serafin, J Michie… - Anticancer …, 2004 - ar.iiarjournals.org
Background: Apoptotic propensity is currently viewed as an important parameter in drug-
induced toxicity. But other cell death pathways exist eg micronucleation, intermitotic cell …
induced toxicity. But other cell death pathways exist eg micronucleation, intermitotic cell …
Relationship between electrochemical potentials and substitution reaction rates of ferrocene-containing β-diketonato rhodium (I) complexes; cytotoxicity of [Rh …
J Conradie, JC Swarts - Dalton Transactions, 2011 - pubs.rsc.org
A series of ferrocene-containing rhodium complexes of the type [Rh (FcCOCHCOR)(cod)](
cod= 1, 5-cyclooctadiene) with R= CF3, 1,(Epa (Rh)= 269; Eo′(Fc)= 329 mV vs. Fc/Fc+) …
cod= 1, 5-cyclooctadiene) with R= CF3, 1,(Epa (Rh)= 269; Eo′(Fc)= 329 mV vs. Fc/Fc+) …
Oxidative Addition of CH3I and CO Migratory Insertion in a Series of Ferrocene-Containing Carbonyl Phosphine β-Diketonato Rhodium(I) Complexes
J Conradie, JC Swarts - Organometallics, 2009 - ACS Publications
A kinetic study of the oxidative addition reaction between CH3I and a series of ferrocene-
containing β-diketonato carbonyl phosphine rhodium (I) complexes [Rh …
containing β-diketonato carbonyl phosphine rhodium (I) complexes [Rh …
Kinetic study of the oxidative addition reaction between methyl iodide and [Rh (FcCOCHCOCF3)(CO)(PPh3)]: Structure of [Rh (FcCOCHCOCF3)(CO)(PPh3)(CH3)(I)]
The kinetics of oxidative addition of CH3I to [Rh (FcCOCHCOCF3)(CO)(PPh3)], where Fc=
ferrocenyl and (FcCOCHCOCF3)−= fctfa= ferrocenoylacetonato, have been studied utilizing …
ferrocenyl and (FcCOCHCOCF3)−= fctfa= ferrocenoylacetonato, have been studied utilizing …