Palladacycles remain a challenging and significant research field in organic chemistry and
have emerged as a type of powerful and versatile precatalysts or key active intermediates for …

Conspectus Allylic amides, amines, and esters are key synthetic building blocks. Their
enantioselective syntheses under mild conditions is a continuing pursuit of organic synthesis …

Tetraazacoronenes were synthesized from bay‐functionalized tetraazaperylenes by Zr‐
mediated cyclization and four‐fold Suzuki–Miyaura cross coupling. In the Zr‐mediated …

Single-chain magnets (SCMs) are one-dimensional (1D) coordination polymers that exhibit
magnetic bistability and have potential application in high-density information processing …

A catalyst of a new type, cyclobutadiene complex [(C4Et4) Rh (p-xylene)] PF6, was found to
promote selective reductive amination in the presence of carbon monoxide under mild …

Metallomacromolecules are attracting considerable attention as a class of macromolecular
materials with unique properties and applications. Although ferrocene (Fc)-containing …

Three new cobalt–ruthenium heterometallic molecular rectangles, 1–3, were synthesized
through the coordination‐driven self‐assembly of a new cobalt sandwich donor,(η5‐Cp) Co …

Synthesis and reactivity of the cyclobutadiene complexes of platinum metals are reviewed.
Palladium and platinum complexes are well developed and are mainly represented by the …

A series of hybrid uranocenes consisting of uranium (IV) sandwiched between
cyclobutadienyl (Cb) and cyclo-octatetraenyl (COT) ligands has been synthesized …

Photolysis of (MePMPMe) 2ZrBn2 (MePMPMe= 3, 5-dimethyl-2-(2-pyridyl) pyrrolide) in the
presence of diphenylacetylene yields the first η4-cyclobutadienyl zirconium …