Optimizing catalyst and reaction conditions in gold (I) catalysis–ligand development
This review considers phosphine and N-heterocyclic carbene complexes of gold (I) that are
used as (pre) catalysts for a range of reactions in organic synthesis. These are divided …
used as (pre) catalysts for a range of reactions in organic synthesis. These are divided …
Preparation and Post-Assembly Modification of Metallosupramolecular Assemblies from Poly(N-Heterocyclic Carbene) Ligands
MM Gan, JQ Liu, L Zhang, YY Wang, FE Hahn… - Chemical …, 2018 - ACS Publications
Although the coordination chemistry of N-heterocyclic carbenes (NHCs) with transition
metals has been explored for half a century, only in the past ten years has the chemistry of …
metals has been explored for half a century, only in the past ten years has the chemistry of …
Main avenues in gold coordination chemistry
RP Herrera, MC Gimeno - Chemical Reviews, 2021 - ACS Publications
In this contribution, we provide an overview of the main avenues that have emerged in gold
coordination chemistry during the last years. The unique properties of gold have motivated …
coordination chemistry during the last years. The unique properties of gold have motivated …
Visual kinetic analysis
CDT Nielsen, J Burés - Chemical science, 2019 - pubs.rsc.org
Visual kinetic analyses extract meaningful mechanistic information from experimental data
using the naked-eye comparison of appropriately modified progress reaction profiles. Basic …
using the naked-eye comparison of appropriately modified progress reaction profiles. Basic …
Recent advances in annellated NHCs and their metal complexes
NUD Reshi, JK Bera - Coordination Chemistry Reviews, 2020 - Elsevier
N-Heterocyclic carbenes (NHCs) have emerged as one of the most useful class of ligands
for metal complexes primarily due to their relatively easy synthesis, broad structural and …
for metal complexes primarily due to their relatively easy synthesis, broad structural and …
A redox-switchable gold (I) complex for the hydroamination of acetylenes: a convenient way for studying ligand-derived electronic effects
A gold complex with a naphthalene-di-imide-functionalized N-heterocyclic carbene (NHC)
ligand was prepared and characterized. The electrochemical studies reveal that the complex …
ligand was prepared and characterized. The electrochemical studies reveal that the complex …
Clippane: a mechanically interlocked molecule (MIM) based on molecular tweezers
In this study we report the preparation of a new mechanically interlocked molecule formed
by the self‐aggregation of two metallotweezers composed by two pyrene‐imidazolylidene …
by the self‐aggregation of two metallotweezers composed by two pyrene‐imidazolylidene …
Stable Au(III) Complexes Bearing Hemilabile P∧N and C∧N Ligands: Coordination of the Pendant Nitrogen upon Oxidation of Gold
The oxidation of Au (I) complexes featuring two hemilabile ligands was investigated. The
phosphine-amine (P∧ N) and mesoionic N-heterocyclic carbene-pyridine (C∧ N) ligands …
phosphine-amine (P∧ N) and mesoionic N-heterocyclic carbene-pyridine (C∧ N) ligands …
A Rigid Trigonal‐Prismatic Hexagold Metallocage That Behaves as a Coronene Trap
A trigonal‐prismatic hexagold cage was obtained by combining a triphenylene‐tris (N‐
heterocyclic carbene) ligand and a carbazolyl‐bis (alkynyl) linker. The metallocage has a …
heterocyclic carbene) ligand and a carbazolyl‐bis (alkynyl) linker. The metallocage has a …
The Complex Coordination Landscape of a Digold (I) U‐Shaped Metalloligand
AU‐shaped di‐gold metallotweezer with two pyrene‐imidazolylidene edges and a xanthenyl‐
bis‐alkynyl connector was prepared. This metallotweezer acts as metalloligand in the …
bis‐alkynyl connector was prepared. This metallotweezer acts as metalloligand in the …