Recent advances in enantioselective Pd-catalyzed allylic substitution: from design to applications
O Pamies, J Margalef, S Canellas, J James… - Chemical …, 2021 - ACS Publications
This Review compiles the evolution, mechanistic understanding, and more recent advances
in enantioselective Pd-catalyzed allylic substitution and decarboxylative and oxidative allylic …
in enantioselective Pd-catalyzed allylic substitution and decarboxylative and oxidative allylic …
Further developments and applications of oxazoline-containing ligands in asymmetric catalysis
The chiral oxazoline motif is present in many ligands that have been extensively applied in a
series of important metal-catalyzed enantioselective reactions. This Review aims to provide …
series of important metal-catalyzed enantioselective reactions. This Review aims to provide …
Enantio‐and Diastereodivergent Synthesis of Spirocycles through Dual‐Metal‐Catalyzed [3+ 2] Annulation of 2‐Vinyloxiranes with Nucleophilic Dipoles
Y Peng, X Huo, Y Luo, L Wu, W Zhang - Angewandte Chemie, 2021 - Wiley Online Library
The development of efficient and straightforward methods for obtaining all optically active
isomers of structurally rigid spirocycles from readily available starting materials is of great …
isomers of structurally rigid spirocycles from readily available starting materials is of great …
Atroposelective Synthesis of 1, 1′‐Bipyrroles Bearing a Chiral N− N Axis: Chiral Phosphoric Acid Catalysis with Lewis Acid Induced Enantiodivergence
Y Gao, LY Wang, T Zhang, BM Yang… - Angewandte Chemie …, 2022 - Wiley Online Library
We present herein a highly efficient atroposelective synthesis of axially chiral 1, 1′‐
bipyrroles bearing an N− N linkage from simple hydrazine and 1, 4‐diones. Further product …
bipyrroles bearing an N− N linkage from simple hydrazine and 1, 4‐diones. Further product …
Recent advances in Pd-catalyzed asymmetric cyclization reactions
B Xu, Q Wang, C Fang, ZM Zhang… - Chemical Society Reviews, 2024 - pubs.rsc.org
Over the past few decades, there have been major developments in transition metal-
catalyzed asymmetric cyclization reactions, enabling the convenient access to a wide …
catalyzed asymmetric cyclization reactions, enabling the convenient access to a wide …
Highly enantioselective [5+ 2] annulations through cooperative N-heterocyclic carbene (NHC) organocatalysis and palladium catalysis
The highly enantioselective [5+ 2] annulation of enals with vinylethylene carbonates through
a cooperative N-heterocyclic carbene (NHC)/Pd catalytic system is reported. The use of a …
a cooperative N-heterocyclic carbene (NHC)/Pd catalytic system is reported. The use of a …
Atroposelective construction of nine‐membered carbonate‐bridged biaryls
We herein demonstrated an efficient method for the atroposelective construction of nine‐
membered carbonate‐bridged biaryls through vinylidene ortho‐quinone methide (VQM) …
membered carbonate‐bridged biaryls through vinylidene ortho‐quinone methide (VQM) …
Stereoselective access to [5.5. 0] and [4.4. 1] bicyclic compounds through Pd-catalysed divergent higher-order cycloadditions
Medium-sized rings, including those embedded in bridged and fused bicyclic scaffolds, are
common core structures of myriad bioactive molecules. Among various synthetic strategies …
common core structures of myriad bioactive molecules. Among various synthetic strategies …
Stereoselective Access to Polyfunctionalized Nine‐Membered Heterocycles by Sequential Gold and Palladium Catalysis
We report herein a gold and palladium sequential catalysis system to access furan‐fused
nine‐membered heterocycles in high efficiency and enantioselectivity. In this one‐pot …
nine‐membered heterocycles in high efficiency and enantioselectivity. In this one‐pot …
Palladium‐Catalyzed Asymmetric [4+ 2] Cycloaddition of 2‐Methylidenetrimethylene Carbonate with Alkenes: Access to Chiral Tetrahydropyran‐Fused Spirocyclic …
B Mao, H Liu, Z Yan, Y Xu, J Xu… - Angewandte Chemie …, 2020 - Wiley Online Library
Abstract A palladium‐catalyzed asymmetric [4+ 2] cycloaddition of 2‐
methylidenetrimethylene carbonate with alkenes derived from pyrazolones, indandione, or …
methylidenetrimethylene carbonate with alkenes derived from pyrazolones, indandione, or …