This Review compiles the evolution, mechanistic understanding, and more recent advances
in enantioselective Pd-catalyzed allylic substitution and decarboxylative and oxidative allylic …

The chiral oxazoline motif is present in many ligands that have been extensively applied in a
series of important metal-catalyzed enantioselective reactions. This Review aims to provide …

The development of efficient and straightforward methods for obtaining all optically active
isomers of structurally rigid spirocycles from readily available starting materials is of great …

We present herein a highly efficient atroposelective synthesis of axially chiral 1, 1′‐
bipyrroles bearing an N− N linkage from simple hydrazine and 1, 4‐diones. Further product …

Over the past few decades, there have been major developments in transition metal-
catalyzed asymmetric cyclization reactions, enabling the convenient access to a wide …

The highly enantioselective [5+ 2] annulation of enals with vinylethylene carbonates through
a cooperative N-heterocyclic carbene (NHC)/Pd catalytic system is reported. The use of a …

We herein demonstrated an efficient method for the atroposelective construction of nine‐
membered carbonate‐bridged biaryls through vinylidene ortho‐quinone methide (VQM) …

Medium-sized rings, including those embedded in bridged and fused bicyclic scaffolds, are
common core structures of myriad bioactive molecules. Among various synthetic strategies …

We report herein a gold and palladium sequential catalysis system to access furan‐fused
nine‐membered heterocycles in high efficiency and enantioselectivity. In this one‐pot …

Abstract A palladium‐catalyzed asymmetric [4+ 2] cycloaddition of 2‐
methylidenetrimethylene carbonate with alkenes derived from pyrazolones, indandione, or …