Tuning the Spin State of Co3+ by Crystal Facet Engineering for Enhancing the Oxygen Evolution Reaction Activity

C Wu, Y Sun, Z Yang, J Hu, TY Ding, J Cheng… - Chemistry of …, 2022 - ACS Publications
The spin configuration is vital for oxygen evolution reaction (OER) activity because it has a
strong effect on the adsorption/desorption ability of electrochemical reaction intermediates …

Electronic parameters in cobalt-based perovskite-type oxides as descriptors for chemocatalytic reactions

J Simböck, M Ghiasi, S Schönebaum, U Simon… - Nature …, 2020 - nature.com
Perovskite-type transition metal (TM) oxides are effective catalysts in oxidation and
decomposition reactions. Yet, the effect of compositional variation on catalytic efficacy is not …

Orbital-overlap-driven hybridization in 3d-transition metal perovskite oxides LaMO3 (M = Ti-Ni) and La2CuO4

CY Liu, L Celiberti, R Decker, K Ruotsalainen… - Communications …, 2024 - nature.com
The wide tunability of strongly correlated transition metal (TM) oxides stems from their
complex electronic properties and the coupled degrees of freedom. Among the perovskite …

Operando Soft X-ray Absorption of LaMn1–xCoxO3 Perovskites for CO Oxidation

Q Che, M Ghiasi, L Braglia, MLJ Peerlings, S Mauri… - ACS …, 2024 - ACS Publications
We employed operando soft X-ray absorption spectroscopy (XAS) to monitor the changes in
the valence states and spin properties of LaMn1–x Co x O3 catalysts subjected to a mixture …

Paramagnetic : A Highly Inhomogeneous Mixed Spin-State System

D Takegami, A Tanaka, S Agrestini, Z Hu, J Weinen… - Physical Review X, 2023 - APS
We investigate the electronic structure of LaCoO 3 across the gradual spin-state and
insulator-to-metal transitions using bulk-sensitive hard x-ray photoelectron and soft x-ray …

Tensile-Strain-Dependent Spin States in Epitaxial Thin Films

Y Yokoyama, Y Yamasaki, M Taguchi, Y Hirata… - Physical Review Letters, 2018 - APS
The spin states of Co 3+ ions in perovskite-type LaCoO 3, governed by the complex
interplay between the electron-lattice interactions and the strong electron correlations, still …

EDRIXS: An open source toolkit for simulating spectra of resonant inelastic x-ray scattering

YL Wang, G Fabbris, MPM Dean, G Kotliar - Computer Physics …, 2019 - Elsevier
Resonant inelastic x-ray scattering (RIXS) has become a very powerful experimental
technique to probe a broad range of intrinsic elementary excitations, for example, from low …

Analyzing the Local Electronic Structure of Co3O4 Using 2p3d Resonant Inelastic X-ray Scattering

RP Wang, MJ Huang, A Hariki, J Okamoto… - The Journal of …, 2022 - ACS Publications
We present the cobalt 2p3d resonant inelastic X-ray scattering (RIXS) spectra of Co3O4.
Guided by multiplet simulation, the excited states at 0.5 and 1.3 eV can be identified as the 4 …

[PDF][PDF] Development of the soft x-ray AGM–AGS RIXS beamline at the Taiwan photon source

A Singh, HY Huang, YY Chu, CY Hua… - Journal of …, 2021 - journals.iucr.org
We report on the development of a high-resolution and highly efficient beamline for soft X-
ray resonant inelastic X-ray scattering (RIXS) located at the Taiwan Photon Source. This …

A New Era of Excitonic Insulators

T Kaneko, Y Ohta - Journal of the Physical Society of Japan, 2025 - journals.jps.jp
The fundamental idea of the excitonic insulator (EI) driven by electron–hole correlations in
narrow-gap semiconductors or semimetals was originally proposed in the 1960s, and only …