Heavier element-containing aromatics of [4 n+ 2]-electron systems
While the implication of the aromaticity concept has been dramatically expanded to date
since its emergence in 1865, the classical [4n+ 2]/4n-electron counting protocol still plays an …
since its emergence in 1865, the classical [4n+ 2]/4n-electron counting protocol still plays an …
Recent progress in the chemistry of metal amidinates and guanidinates: syntheses, catalysis and materials
FT Edelmann - Advances in organometallic chemistry, 2013 - Elsevier
This review provides a comprehensive overview of the most recent progress in chemistry
and applications of metal complexes containing heteroallylic ligands such as amidinates …
and applications of metal complexes containing heteroallylic ligands such as amidinates …
π-Aromaticity Dominating in a Saturated Ring: Neutral Aromatic Silicon Analogues of Cyclobutane-1, 3-diyls
Y Li, S Dong, J Guo, Y Ding, J Zhang… - Journal of the …, 2023 - ACS Publications
The synthesis, structures, and reactivity of the first neutral 2π-aromatic Si4 rings [LSiSiAr (X)]
2 (3: X= Br; 4: X= Cl; L= PhC (NtBu) 2, Ar= 2, 4, 6-Me3C6H2) were described. Compounds 3 …
2 (3: X= Br; 4: X= Cl; L= PhC (NtBu) 2, Ar= 2, 4, 6-Me3C6H2) were described. Compounds 3 …
Diels–Alder reactivities of benzene, pyridine, and di-, tri-, and tetrazines: The roles of geometrical distortions and orbital interactions
The cycloadditions of benzene and ten different azabenzenes (pyridine, three diazines,
three triazines, and three tetrazines) with the ethylene dienophile have been explored with …
three triazines, and three tetrazines) with the ethylene dienophile have been explored with …
Stabilizing Two Classical Antiaromatic Frameworks: Demonstration of Photoacoustic Imaging and the Photothermal Effect in Metalla‐aromatics
Antiaromatic species are substantially less thermodynamically stable than aromatic
moieties. Herein, we report the stabilization of two classical antiaromatic frameworks …
moieties. Herein, we report the stabilization of two classical antiaromatic frameworks …
Pnictogen–Silicon Analogues of Benzene
AE Seitz, M Eckhardt, A Erlebach… - Journal of the …, 2016 - ACS Publications
Since the discovery of the first “inorganic benzene”(borazine, B3N3H6), the synthesis of
other noncarbon derivatives is an ongoing challenge in Inorganic Chemistry. Here we report …
other noncarbon derivatives is an ongoing challenge in Inorganic Chemistry. Here we report …
Evaluation of triplet aromaticity by the isomerization stabilization energy
J Zhu, K An, PR Schleyer - Organic letters, 2013 - ACS Publications
The many manifestations of aromaticity have long fascinated both experimentalists and
theoreticians. Due to their degenerate half-filled MOs, triplet [n] annulenes with 4 n π …
theoreticians. Due to their degenerate half-filled MOs, triplet [n] annulenes with 4 n π …
Triplet state aromaticity: NICS criterion, hyperconjugation, and charge Effects
H Sun, K An, J Zhu - Chemistry–An Asian Journal, 2016 - Wiley Online Library
Aromaticity, one of the most important concepts in organic chemistry, has attracted
considerable interest from both experimentalists and theoreticians. It remains unclear which …
considerable interest from both experimentalists and theoreticians. It remains unclear which …
An Electrophilic Carbene‐Anchored Silylene–Phosphinidene
The cyclic alkyl (amino) carbene‐anchored silylene–phosphinidene was isolated as L− Si−
P (: cAAC− Me)(L= benzamidinate) at room temperature, synthesized from the reduction of …
P (: cAAC− Me)(L= benzamidinate) at room temperature, synthesized from the reduction of …