Fluorinated pyrazoles: From synthesis to applications
PK Mykhailiuk - Chemical Reviews, 2020 - ACS Publications
Fluorinated pyrazoles play an important role in medicinal chemistry, drug discovery,
agrochemistry, coordination chemistry, and organometallic chemistry. Since the early 1990s …
agrochemistry, coordination chemistry, and organometallic chemistry. Since the early 1990s …
Coinage-metal-based cyclic trinuclear complexes with metal–metal interactions: theories to experiments and structures to functions
Among the d10 coinage metal complexes, cyclic trinuclear complexes (CTCs) or trinuclear
metallocycles with intratrimer metal–metal interactions are fascinating and important metal …
metallocycles with intratrimer metal–metal interactions are fascinating and important metal …
The chemistry and applications of flexible porous coordination polymers
Since the late 1990s, much progress has been made in the field of the chemistry of flexible
porous coordination polymers (PCPs). Various PCP architectures have been recognized …
porous coordination polymers (PCPs). Various PCP architectures have been recognized …
2,2,2-Trifluorodiazoethane (CF3CHN2): A Long Journey since 1943
PK Mykhailiuk - Chemical Reviews, 2020 - ACS Publications
2, 2, 2-Trifluorodiazoethane (CF3CHN2) has been proven to be a valuable reagent for the
rapid synthesis of various classes of trifluoromethyl-substituted organic molecules in both …
rapid synthesis of various classes of trifluoromethyl-substituted organic molecules in both …
Construction of Cu (I)-organic frameworks with effective sorption behavior for iodine and congo red
ZZ Xue, YL Wang, Y Zhang, GY Fan, SD Han… - Inorganic …, 2022 - ACS Publications
The assembly of a tetradentate pyridine-derived ligand with CuX has afforded two
isostructural Cu (I)-organic frameworks [Cu2X2 (TBD)· DMF] n (X= Cl for 1 and Br for 2) in …
isostructural Cu (I)-organic frameworks [Cu2X2 (TBD)· DMF] n (X= Cl for 1 and Br for 2) in …
The π-acidity/basicity of cyclic trinuclear units (CTUs): from a theoretical perspective to potential applications
Cyclic trinuclear units (CTUs) based on Au (I), Ag (I) and Cu (I) cations, featuring near planar
nine-membered coordination rings, represent an important class of metal–organic π …
nine-membered coordination rings, represent an important class of metal–organic π …
A Molecular Compound for Highly Selective Purification of Ethylene
Purification of C2H4 from an C2H4/C2H6 mixture is one of the most challenging separation
processes, which is achieved mainly through energy‐intensive, cryogenic distillation in …
processes, which is achieved mainly through energy‐intensive, cryogenic distillation in …
Enhancing the separation efficiency of a C 2 H 2/C 2 H 4 mixture by a chromium metal–organic framework fabricated via post-synthetic metalation
F Yu, BQ Hu, XN Wang, YM Zhao, JL Li, B Li… - Journal of Materials …, 2020 - pubs.rsc.org
Chromium metal–organic frameworks (MOFs) are well-known for their stable porous
frameworks, which are not fully explored due to the difficulty encountered in the synthesis …
frameworks, which are not fully explored due to the difficulty encountered in the synthesis …
When SF 5 outplays CF 3: effects of pentafluorosulfanyl decorated scorpionates on copper
A Noonikara-Poyil, A Muñoz-Castro, A Boretskyi… - Chemical …, 2021 - pubs.rsc.org
Polyfluorinated, electron-withdrawing, and sterically demanding supporting ligands are of
significant value in chemistry. Here we report the assembly and use of a bis (pyrazolyl) …
significant value in chemistry. Here we report the assembly and use of a bis (pyrazolyl) …
Acetylene and terminal alkyne complexes of copper (I) supported by fluorinated pyrazolates: Syntheses, structures, and transformations
Trinuclear {μ-[3, 5-(CF3) 2Pz] Cu} 3 reacts with acetylene to produce the 2: 1 copper (I)
acetylene complex, Cu4 (μ-[3, 5-(CF3) 2Pz]) 4 (μ-HCCH) 2. Related Cu4 (μ-[4-Br-3, 5-(CF3) …
acetylene complex, Cu4 (μ-[3, 5-(CF3) 2Pz]) 4 (μ-HCCH) 2. Related Cu4 (μ-[4-Br-3, 5-(CF3) …