Examining the role of nucleating agents within glass-ceramic systems

AV DeCeanne, LR Rodrigues, CJ Wilkinson… - Journal of Non …, 2022 - Elsevier
Nucleation is one of the primary contributions to the microstructure of glass-ceramics.
However, the nucleation process within glass-ceramics is not understood across all glass …

Nucleation, growth, and crystallization in oxide glass-formers. A current perspective

M Montazerian, ED Zanotto - Reviews in Mineralogy …, 2022 - pubs.geoscienceworld.org
Vitrification from the molten state hinges on averting crystallization during the cooling path.
On the other hand, critical natural processes, such as the formation of snow and igneous …

ViscNet: Neural network for predicting the fragility index and the temperature-dependency of viscosity

DR Cassar - Acta materialia, 2021 - Elsevier
Viscosity is one of the most important properties of disordered matter. The temperature-
dependence of viscosity is used to adjust process variables for glass-making, from melting to …

Hybrid machine learning/physics-based approach for predicting oxide glass-forming ability

CJ Wilkinson, C Trivelpiece, R Hust, RS Welch… - Acta Materialia, 2022 - Elsevier
Predicting the liquid compositions that will vitrify at experimentally accessible quench rates
remains one of the grand challenges in the field of condensed matter physics. This glass …

Viscosity and liquidus‐based predictor of glass‐forming ability of oxide glasses

J Jiusti, ED Zanotto, DR Cassar… - Journal of the …, 2020 - Wiley Online Library
Glass‐forming ability (GFA) is a measure of the easiness to vitrify a given substance.
Theoretically, it is possible to make a glass from any liquid provided it is quenched from its …

The race within supercooled liquids—Relaxation versus crystallization

ED Zanotto, DR Cassar - The Journal of Chemical Physics, 2018 - pubs.aip.org
Can any liquid be cooled down below its melting point to an isentropic (Kauzmann)
temperature without vitrifying or crystallizing? This long-standing question concerning the …

Transition zone theory compared to standard models: reexamining the theory of crystal growth from melts

JD Martin, BG Hillis, F Hou - The Journal of Physical Chemistry C, 2020 - ACS Publications
Ideas proposed at the beginning of the 20th century to describe the temperature
dependence of crystal growth rates have become accepted as the “standard model.” …

Accelerated crystal growth in a lithia aluminosilicate glass

J Löschmann, P Fielitz, G Helsch, H Bornhöft… - Acta Materialia, 2022 - Elsevier
No viscosity change in the vicinity of the crystal/melt interface is to be expected for crystal
growth in silicate systems at constant temperature in a deeply undercooled isochemical …

Catalytic mechanism of iron oxide doping on the crystallization process of Cr2O3-containg glass ceramics

Y Shi, X Song, X Han - Journal of Non-Crystalline Solids, 2021 - Elsevier
The influence of Fe 2 O 3 addition to the nucleation process of Cr 2 O 3-containing CaO-
MgO-Al 2 O 3-SiO 2 (CAMS) based glass ceramic was investigated by Raman spectroscopy …

Crystal growth in oxide melts—From CALPHAD thermodynamic modeling to statistical prediction

L Ueberricke, T Murata, H Ikeda, S Nakane… - Acta Materialia, 2024 - Elsevier
Using a thermodynamic database approach (CALPHAD), thermodynamic parameters of
crystal growth of 31 stoichiometric and non-stoichiometric glasses are calculated. Together …