Emerging applications for living crystallization-driven self-assembly

L MacFarlane, C Zhao, J Cai, H Qiu, I Manners - Chemical Science, 2021 - pubs.rsc.org
The use of crystallization as a tool to control the self-assembly of polymeric and molecular
amphiphiles in solution is attracting growing attention for the creation of non-spherical …

Functional supramolecular aggregates based on BODIPY and aza-BODIPY dyes: control over the pathway complexity

Z Chen, Z Chen - Organic Chemistry Frontiers, 2023 - pubs.rsc.org
Boron-dipyrromethene (BODIPY) and boron-azadipyrromethene (aza-BODIPY) dyes are
attractive candidates for versatile building blocks for functional supramolecular dye …

Nanoengineering of curved supramolecular polymers: toward single-chain mesoscale materials

S Datta, S Takahashi, S Yagai - Accounts of Materials Research, 2022 - ACS Publications
Conspectus Recently, supramolecular polymers (SPs), which depend on the formation of
reversible bonds between monomers, have attracted attention as a class of materials that …

Pathway complexity in supramolecular copolymerization and blocky star copolymers by a hetero-seeding effect

P Khanra, AK Singh, L Roy, A Das - Journal of the American …, 2023 - ACS Publications
This study unravels the intricate kinetic and thermodynamic pathways involved in the
supramolecular copolymerization of the two chiral dipolar naphthalene monoimide (NMI) …

Pathway and length control of supramolecular polymers in aqueous media via a hydrogen bonding lock

I Helmers, G Ghosh, RQ Albuquerque… - Angewandte Chemie …, 2021 - Wiley Online Library
Programming the organization of π‐conjugated systems into nanostructures of defined
dimensions is a requirement for the preparation of functional materials. Herein, we have …

Crystallization‐Driven Controlled Two‐Dimensional (2D) Assemblies from Chromophore‐Appended Poly (L‐lactide) s: Highly Efficient Energy Transfer on a 2D …

A Rajak, A Das - Angewandte Chemie International Edition, 2022 - Wiley Online Library
A rational approach towards precision two‐dimensional (2D) assemblies by crystallization‐
driven self‐assembly (CDSA) of poly (L‐lactides)(PLLAs), end‐capped with dipolar dyes like …

Control over multiple nano‐and secondary structures in peptide self‐assembly

G Ghosh, R Barman, A Mukherjee… - Angewandte Chemie …, 2022 - Wiley Online Library
Herein, we report the rich morphological and conformational versatility of a biologically
active peptide (PEP‐1), which follows diverse self‐assembly pathways to form up to six …

Dual trapping of a metastable planarized triarylborane π-system based on folding and lewis acid–base complexation for seeded polymerization

H Choi, S Ogi, N Ando… - Journal of the American …, 2021 - ACS Publications
We report the kinetically controlled supramolecular polymerization of boron-containing π-
conjugated molecules, which was enabled by a seeding method based on dual trapping of a …

Living supramolecular polymerization of fluorinated cyclohexanes

O Shyshov, SV Haridas, L Pesce, H Qi, A Gardin… - Nature …, 2021 - nature.com
The development of powerful methods for living covalent polymerization has been a key
driver of progress in organic materials science. While there have been remarkable reports …

Three‐Component Multiblock 1D Supramolecular Copolymers of Ir (III) Complexes with Controllable Sequences

Y Chen, Q Wan, Y Shi, B Tang… - Angewandte Chemie …, 2023 - Wiley Online Library
Multicomponent supramolecular block copolymers (BCPs) have attracted much attention
due to their potential functionalities, but examples of three‐component supramolecular …