Advances in the use of CO 2 as a renewable feedstock for the synthesis of polymers

B Grignard, S Gennen, C Jérôme, AW Kleij… - Chemical Society …, 2019 - pubs.rsc.org
Carbon dioxide offers an accessible, cheap and renewable carbon feedstock for synthesis.
Current interest in the area of carbon dioxide valorisation aims at new, emerging …

Recent progress in the catalytic transformation of carbon dioxide into biosourced organic carbonates

V Aomchad, À Cristòfol, F Della Monica, B Limburg… - Green …, 2021 - pubs.rsc.org
Cyclic organic carbonates are among the most widely studied targets in the nonreductive
conversion of carbon dioxide using oxiranes as the common reaction partners. Apart from …

Biobased amines: from synthesis to polymers; present and future

V Froidevaux, C Negrell, S Caillol, JP Pascault… - Chemical …, 2016 - ACS Publications
Amines are key intermediates in the chemical industry due to their nucleophilic characteristic
which confers a high reactivity to them. Thus, they are key monomers for the synthesis of …

Organocatalyzed coupling of carbon dioxide with epoxides for the synthesis of cyclic carbonates: catalyst design and mechanistic studies

M Alves, B Grignard, R Méreau, C Jerome… - Catalysis Science & …, 2017 - pubs.rsc.org
The coupling of carbon dioxide (CO2) with epoxides with the formation of cyclic carbonates
is a highly attractive 100% atom economic reaction. It represents a greener and safer …

Isocyanate-free routes to polyurethanes and poly (hydroxy urethane) s

L Maisonneuve, O Lamarzelle, E Rix, E Grau… - Chemical …, 2015 - ACS Publications
In the current context of sustainable chemistry development and new regulations, research
groups and industries have to replace hazardous chemicals and harsh reaction conditions …

A perspective approach to sustainable routes for non-isocyanate polyurethanes

A Cornille, R Auvergne, O Figovsky, B Boutevin… - European Polymer …, 2017 - Elsevier
Sustainable routes for the synthesis of polyurethanes with industrial applications are
discussed in this article. Polyurethane is currently one of the most commonly used polymers …

From the synthesis of biobased cyclic carbonate to polyhydroxyurethanes: a promising route towards renewable non‐isocyanate polyurethanes

C Carré, Y Ecochard, S Caillol, L Avérous - ChemSusChem, 2019 - Wiley Online Library
With a global production of around 18 million tons (6th among all polymers) and a wide
range of applications, such as rigid and soft foams, elastomers, coatings, and adhesives …

Non‐isocyanate polyurethanes: synthesis, properties, and applications

G Rokicki, PG Parzuchowski… - Polymers for Advanced …, 2015 - Wiley Online Library
Conventional polyurethanes are typically obtained from polyisocyanates, polyols, and chain
extenders. The main starting materials—isocyanates used in this process—raise severe …

A review of fatty epoxide ring opening reactions: Chemistry, recent advances, and applications

BR Moser, SC Cermak, KM Doll… - Journal of the …, 2022 - Wiley Online Library
Fatty epoxides are produced from the corresponding alkenes by oxidation in the presence of
peracids or other oxidants. The classic method is the Prilezhaev epoxidation in which …

Synthesis of polyurethanes using organocatalysis: A perspective

H Sardon, A Pascual, D Mecerreyes, D Taton… - …, 2015 - ACS Publications
Organocatalysis has become an invaluable tool for polymer synthesis, and its utility has
been demonstrated in ring-opening, anionic, zwitterionic, and group-transfer …