Photoinduced structural dynamics of molecular systems mapped by time-resolved X-ray methods

M Chergui, E Collet - Chemical reviews, 2017 - ACS Publications
We review the tremendous advances in ultrafast X-ray science, over the past 15 years,
making the best use of new ultrashort X-ray sources including table-top or large-scale …

Ultrafast X-ray crystallography and liquidography

H Ki, KY Oang, J Kim, H Ihee - Annual Review of Physical …, 2017 - annualreviews.org
Time-resolved X-ray diffraction provides direct information on three-dimensional structures
of reacting molecules and thus can be used to elucidate structural dynamics of chemical and …

Multigrain crystallography

HO Sørensen, S Schmidt, JP Wright, GBM Vaughan… - 2012 - degruyter.com
We summarize exploratory work on multigrain crystallography. The experimental
arrangement comprises a monochromatic beam, a fully illuminated sample with up to …

Ultrafast spin-state photoswitching in a crystal and slower consecutive processes investigated by femtosecond optical spectroscopy and picosecond X-ray diffraction

E Collet, N Moisan, C Baldé, R Bertoni… - Physical Chemistry …, 2012 - pubs.rsc.org
We report the spin state photo-switching dynamics in two polymorphs of a spin-crossover
molecular complex triggered by a femtosecond laser flash, as determined by combining …

Axial vs equatorial: Capturing the intramolecular charge transfer state geometry in conformational polymorphic crystals of a donor–bridge–acceptor dyad in …

K Basuroy, JJ Velazquez-Garcia, D Storozhuk… - The Journal of …, 2023 - pubs.aip.org
Two conformational polymorphs of a donor–bridge–acceptor (DBA) dyad, p-(CH 3) 2 NC 6 H
4-(CH 2) 2-(1-pyrenyl)/PyCHDMA, were studied, where the electron donor (D) moiety p-(CH …

Nanosecond-Lived Excimer Observation in a Crystal of a Rhodium (I) Complex via Time-Resolved X-ray Laue Diffraction

P Łaski, L Bosman, J Drapała, R Kamiński… - The Journal of …, 2024 - ACS Publications
The rare observation of transient Rh··· Rh excimer formation in a single crystal is reported.
The estimated excited-state lifetime at 100 K is 2 ns, which makes it the shortest-lived small …

Solvent-Dependent Molecular Structure of Ionic Species Directly Measured<? format?> by Ultrafast X-Ray Solution Scattering

KH Kim, JH Lee, J Kim, S Nozawa, T Sato, A Tomita… - Physical review …, 2013 - APS
Ionic species often play important roles in chemical reactions occurring in water and other
solvents, but it has been elusive to determine the solvent-dependent molecular structure …

Restricted photochemistry in the molecular solid state: structural changes on photoexcitation of Cu (I) phenanthroline metal-to-ligand charge transfer (MLCT) …

A Makal, J Benedict, E Trzop, J Sokolow… - The Journal of …, 2012 - ACS Publications
The excited-state structure of [CuI [(1, 10-phenanthroline-N, N′) bis (triphenylphosphine)]
cations in their crystalline [BF4] salt has been determined at both 180 and 90 K by single …

Statistical analysis of multipole-model-derived structural parameters and charge-density properties from high-resolution X-ray diffraction experiments

R Kamiński, S Domagała, KN Jarzembska… - … A: Foundations and …, 2014 - journals.iucr.org
A comprehensive analysis of various properties derived from multiple high-resolution X-ray
diffraction experiments is reported. A total of 13 charge-density-quality data sets of α-oxalic …

Dynamic single-crystal diffraction studies using synchrotron radiation

LE Hatcher, PR Raithby - Coordination Chemistry Reviews, 2014 - Elsevier
The methods that have been developed to determine the three-dimensional crystal and
molecular structures while they are in metastable or short-lived photoactivated states are …