Conspectus Over recent decades, N-sulfonylhydrazones have attracted significant attention
in academic and industrial contexts owing to their ease of preparation, versatile reactivity …

Abstract (Deuterium‐labeled) CF2H‐and CFH2‐moieties are of high interest in drug
discovery. The high demand for the incorporation of these fluoroalkyl moieties into molecular …

Fluorinated carbenes take an important position in the synthesis of fluorine-containing
molecules in organic synthesis. When carbon centered carbenes are installed with fluorides …

The conversion of easily available trifluoromethylarenes through C–F bond activation
provides an attractive pathway for rapid access to difluorobenzylic substructures in …

C− F insertion of carbon‐atom units is underdeveloped although it poses significant
potential applications in both drug discovery and development. Herein, we report a …

The selective functionalization of trifluoromethyl groups through C–F cleavage poses a
significant challenge due to the high bond energy of the C (sp3)–F bonds. Herein, we …

Visible-light-promoted site-selective and direct C–F bond functionalization of polyfluorinated
iminosulfides was accomplished with alkenes and water under redox-neutral conditions …

Selective defluorinative functionalization of trifluoromethyl ketones is a long‐standing
challenge owing to the exhaustive mode of the process. To meet the demands for the …

A unique and efficient copper catalytic system has been established to synthesize
fluorinated 2-azadienes from isoxazoles and CF3-N-tosylhydrazones via crosscoupling …

The hydride anion addition catalysed by Zn2+ enables the stereoselective and
regioselective hydrodefluorination of fluoroolefins and polyfluoroarenes. This method allows …