Innovative synthetic coordination and, increasingly, organometallic chemistry are at the
heart of advances in molecular magnetism. Smart ligand design is essential for …

Iron is the most abundant transition metal in Earth, s crust; it is relatively inexpensive, not
very toxic, and environmentally benign. 1 Undoubtedly, due to the involvement in a multitude …

Selective functionalization of unactivated C–H bonds and ammonia production are
extremely important industrial processes. A range of metalloenyzmes achieve these …

N-Heterocyclic carbenes (NHCs) are nowadays ubiquitous and indispensable as ancillary
ligands in organotransition metal chemistry, with an enormous variety of NHC types known …

N-Heterocyclic carbene (NHC) ligands are attracting worldwide interest because of their
considerable scope and potential in coordination/organometallic chemistry, catalysis and …

The four-coordinate Fe (II) complex, PhB (MesIm) 3Fe-N PPh3 (1) has been previously
reported to undergo a thermal spin-crossover (SCO) between high-spin (HS, S= 2) and low …

The use of N-heterocyclic carbenes (NHCs) in the chemistry of iron is stimulating important
new applications of one of the most ubiquitous ligand types in modern organometallic …

Bis (formazanate) iron (II) complexes undergo a thermally induced S= 0 to S= 2 spin
transition in solution. Here we present a study of how steric effects and π-stacking …

A new supporting ligand, t ris-[2-(3-mesityl-im idazol-2-ylidene) m ethyl] ami ne
(TIMMNMes), was developed and utilized to isolate an air-stable iron (V) complex bearing a …

Organic diradicals are uncommon species that have been intensely studied for their unique
properties and potential applicability in a diverse range of innovative fields. While there is a …