This third review in a series involving reactions of hydrosilanes and transition metal
complexes and characterization of the products covers the period 2009 thru 2013. After a …

For a long time, Zintl ions of Group 14 and 15 elements were considered to be remarkable
species domiciled in solid‐state chemistry that have unexpected stoichiometries and …

Clusters have been the subject of intense investigations since their famous definition
launched by Cotton in 1963, and the area has expanded ever since. One obvious …

The continuously decreasing size of device features in microelectronics draws growing
attention to the structuring of silicon at the molecular level with powerful tools provided by …

Lange Zeit betrachtete man die Zintl‐Ionen der Elemente der 14. und 15. Gruppe für
bemerkenswerte, in der Festkörperchemie angesiedelte Spezies, die einerseits durch ihre …

The solution chemistry of Group 14 Zintl-type clusters is of growing interest as a result of
their potential to be used as molecular building blocks for the construction of nanoscale …

This manuscript describes skeletal isomerization strategies to install one to four quaternary
germanium atoms in the sila-adamantane core, in a cluster analogy to precision germanium …

Originally, the concepts of aromaticity and antiaromaticity were introduced to explain the
stability and reactivity of unsaturated organic compounds. Since then, they have been …

Atom‐precise, ligand‐stabilized metalloid clusters have emerged as outstanding model
systems to study fundamental structure and bonding situations of compositionally related …

This perspective summarizes highlights and most recent advances in tin cluster chemistry,
thereby addressing the whole diversity of (mostly) discrete units containing tin atoms …