Copper-catalyzed decarboxylative reactions of propargylic cyclic carbonates/carbamates
enable the efficient construction of widely available skeletons such as allenes, ethynyl …

Functionalized cyclic organic carbonates and carbamates are frequently used in a number
of transition metal-catalyzed decarboxylative reactions for the construction of interesting …

Abstract Highly enantioselective [3+ 3] and [3+ 4] annulations of isatin‐derived enals with
ethynylethylene carbonates and ethynyl benzoxazinanones are enabled by NHC/cooper …

Stereoisomers of drugs can have different therapeutic outcomes or side effects, and
regulatory agencies require the bioactivity of all stereoisomers of pharmaceutical candidates …

A copper-catalyzed diastereo-and enantioselective decarboxylative [3+ 2] cyclization
reaction of alkyne-substituted cyclic carbamates with azlactones has been established. A …

Azlactones, also known as oxazolones, are versatile building blocks in organic synthesis
due to the presence of multiple pro‐nucleophilic and electrophilic reactive sites. Recently …

The wide abundance of γ-lactones in natural products and bioactive targets calls for suitable
building blocks for their enantioselective synthesis. β, γ-Unsaturated γ-butenolides …

Transition-metal-catalyzed asymmetric allylic alkylation is one of the most powerful and well-
known strategies for the construction of C–C bonds; nevertheless, propargylation is elusive …

Copper-catalyzed enantioselective propargylic substitution has become an increasingly
reliable strategy to construct stereogenic centers over the past two decades. Currently …

Phosphine-catalyzed enantioselective formal (4+ 2)-cycloadditions of 2-(4 H-benzo [d][1, 3]
oxazin-4-yl) acrylates with isocyanates have been developed for the first time. The initial …