Recent advances in gold (III) chemistry: structure, bonding, reactivity, and role in homogeneous catalysis

L Rocchigiani, M Bochmann - Chemical Reviews, 2020 - ACS Publications
Over the past decade the organometallic chemistry of gold (III) has seen remarkable
advances. This includes the synthesis of the first examples of several compound classes that …

Gold-catalyzed synthesis of small rings

M Mato, A Franchino, C Garcı́a-Morales… - Chemical …, 2020 - ACS Publications
Three-and four-membered rings, widespread motifs in nature and medicinal chemistry, have
fascinated chemists ever since their discovery. However, due to energetic considerations …

Gold (I)-catalyzed activation of alkynes for the construction of molecular complexity

R Dorel, AM Echavarren - Chemical reviews, 2015 - ACS Publications
For centuries, gold had been considered a precious, purely decorative inert metal. It was not
until 1986 that Ito and Hayashi described the first application of gold (I) in homogeneous …

Transition metal-mediated synthesis of monocyclic aromatic heterocycles

AV Gulevich, AS Dudnik, N Chernyak… - Chemical …, 2013 - ACS Publications
Transition Metal-Mediated Synthesis of Monocyclic Aromatic Heterocycles | Chemical Reviews
ACS ACS Publications C&EN CAS Find my institution Log In Chemical Reviews ACS …

Gold catalysis in total synthesis—an update

M Rudolph, ASK Hashmi - Chemical Society Reviews, 2012 - pubs.rsc.org
Gold catalysis in total synthesis—an update - Chemical Society Reviews (RSC Publishing)
DOI:10.1039/C1CS15279C Royal Society of Chemistry View PDF VersionPrevious ArticleNext …

Gold-catalyzed nucleophilic cyclization of functionalized allenes: a powerful access to carbo-and heterocycles

N Krause, C Winter - Chemical reviews, 2011 - ACS Publications
Allenes are highly valuable synthetic precursors in preparative organic chemistry because of
their ability to undergo a variety of transformations. 1 Among many different reaction modes …

Development of catalysts and ligands for enantioselective gold catalysis

YM Wang, AD Lackner, FD Toste - Accounts of chemical research, 2014 - ACS Publications
During the past decade, the use of Au (I) complexes for the catalytic activation of C–C π-
bonds has been investigated intensely. Over this time period, the development of …

Gold-catalyzed cycloisomerizations of enynes: a mechanistic perspective

E Jimenez-Nunez, AM Echavarren - Chemical reviews, 2008 - ACS Publications
Gold salts and complexes have emerged in the past few years as the most powerful
catalysts for electrophilic activation of alkynes toward a variety of nucleophiles under …

Ligand effects in homogeneous Au catalysis

DJ Gorin, BD Sherry, FD Toste - Chemical reviews, 2008 - ACS Publications
Despite the ubiquity of metallic gold (Au) in popular culture, its deployment in homogeneous
catalysis has only recently undergone widespread investigation. In the past decade, and …

Gold-catalyzed organic transformations

Z Li, C Brouwer, C He - Chemical reviews, 2008 - ACS Publications
Thanks to its unusual stability, metallic gold has been used for thousands of years in jewelry,
currency, chinaware, and so forth. However, gold had not become the chemists'“precious …