Hydrogen emerges as one of the cleanest and most renewable energy resources for fossil
fuel alternatives. Commercial-scale hydrogen production through water-splitting …

Efficient hydrogen generation from aqueous protons through direct conversion of solar
energy is an essential prerequisite of a future hydrogen economy and easily accessible …

In this (tutorial overview) perspective we highlight the use of “redox non-innocent” ligands in
catalysis. Two main types of reactivity in which the redox non-innocent ligand is involved can …

Controlled ligand‐based redox‐activity and chemical non‐innocence are rapidly gaining
importance for selective (catalytic) processes. This Concept aims to provide an overview of …

Electrocatalytic hydrogen evolution reaction (HER) is a critical process in a sustainable
energy conversion system. Many metal complexes as small-molecule catalysts for …

This review discusses the use of multidentate actor ligands as new inroads to small
molecule activation and catalysis. Bio-inspired strategies such as the use of redox-active …

Background: Many rhenium (Re) complexes with potential anticancer properties have been
synthesized in the recent years with the aim to overcome the clinical limitations of platinum …

The first section provides a background to the whole review. The second presents a
historical perspective of fundamental developments in rhenium chemistry from its discovery …

The construction of C–S bonds is of great importance in the field of synthetic and medicinal
chemistry. Herein, solvent-induced umpolung reactions from dioxygenation to interligand C …

This Communication describes the use of porous coordination polymers (PCP) with
integrated metal bis (dithiolene) units to achieve electrochemically controlled capture and …