Critical enzyme reactions in aromatic catabolism for microbial lignin conversion
The application of microbes to valorize aromatic compounds derived from the abundant
plant biopolymer lignin is a rapidly developing area of research that may ultimately enable …
plant biopolymer lignin is a rapidly developing area of research that may ultimately enable …
[HTML][HTML] Flavoprotein monooxygenases: versatile biocatalysts
Flavoprotein monooxygenases (FPMOs) are single-or two-component enzymes that
catalyze a diverse set of chemo-, regio-and enantioselective oxyfunctionalization reactions …
catalyze a diverse set of chemo-, regio-and enantioselective oxyfunctionalization reactions …
Gut microbiome of mealworms (Tenebrio molitor Larvae) show similar responses to polystyrene and corn straw diets
Background Some insects can degrade both natural and synthetic plastic polymers, their
host and gut microbes play crucial roles in this process. However, there is still a scientific …
host and gut microbes play crucial roles in this process. However, there is still a scientific …
Enzymatic Hydroxylations of sp3-Carbons
Enzymatic hydroxylation of activated and nonactivated sp3-carbons attracts keen interest
from the chemistry community as it is one of the most challenging tasks in organic synthesis …
from the chemistry community as it is one of the most challenging tasks in organic synthesis …
Unifying and versatile features of flavin-dependent monooxygenases: Diverse catalysis by a common C4a-(hydro) peroxyflavin
A Phintha, P Chaiyen - Journal of Biological Chemistry, 2023 - ASBMB
Flavin-dependent monooxygenases (FDMOs) are known for their remarkable versatility and
for their crucial roles in various biological processes and applications. Extensive research …
for their crucial roles in various biological processes and applications. Extensive research …
Microbial degradation of halogenated aromatics: molecular mechanisms and enzymatic reactions
P Pimviriyakul, T Wongnate, R Tinikul… - Microbial …, 2020 - Wiley Online Library
Halogenated aromatics are used widely in various industrial, agricultural and household
applications. However, due to their stability, most of these compounds persist for a long time …
applications. However, due to their stability, most of these compounds persist for a long time …
Non-Native Site-Selective Enzyme Catalysis
D Mondal, HM Snodgrass, CA Gomez… - Chemical …, 2023 - ACS Publications
The ability to site-selectively modify equivalent functional groups in a molecule has the
potential to streamline syntheses and increase product yields by lowering step counts …
potential to streamline syntheses and increase product yields by lowering step counts …
Reductive Dehalogenation of Herbicides Catalyzed by Pd0NPs in a H2-Based Membrane Catalyst-Film Reactor
More food production required to feed humans will require intensive use of herbicides to
protect against weeds. The widespread application and persistence of herbicides pose …
protect against weeds. The widespread application and persistence of herbicides pose …
Flavin‐N5OOH Functions as both a Powerful Nucleophile and a Base in the Superfamily of Flavoenzymes
Q Zhang, Q Chen, S Shaik… - Angewandte Chemie …, 2024 - Wiley Online Library
Flavoenzymes can mediate a large variety of oxidation reactions through the activation of
oxygen. However, the O2 activation chemistry of flavin enzymes is not yet fully exploited …
oxygen. However, the O2 activation chemistry of flavin enzymes is not yet fully exploited …
Structural and Mechanistic Studies on Substrate and Stereoselectivity of the Indole Monooxygenase VpIndA1: New Avenues for Biocatalytic Epoxidations and …
J Kratky, D Eggerichs, T Heine… - Angewandte Chemie …, 2023 - Wiley Online Library
Flavoprotein monooxygenases are a versatile group of enzymes for biocatalytic
transformations. Among these, group E monooxygenases (GEMs) catalyze enantioselective …
transformations. Among these, group E monooxygenases (GEMs) catalyze enantioselective …