One field of organometallic chemistry that has seen great advancements over the last 20
years is that of main-group chemistry, in particular boron chemistry, that has led to a wealth …

Understanding the chemical behavior of actinide elements is essential for the effective
management and use of actinide materials. In this study, we report an unprecedented η2 …

A room temperature stable complex formulated as Y (NHAr*) 2 has been prepared, where
Ar*= 2, 6-(2, 4, 6-(iPr) 3C6H2) C6H3, by KC8 reduction of ClY (NHAr*) 2. Based on EPR …

Uranium nitrides are important materials with potential for application as fuels for nuclear
power generation, and as highly active catalysts. Molecular nitride compounds could …

The geometrical and electronic structures of Ln [(H2O) 9] 3+ and [Ln (BTP) 3] 3+, where Ln=
Ce–Lu, have been evaluated at the density functional level of theory using three related …

The electronic structure of a series of uranium and cerium hexachlorides in a variety of
oxidation states was evaluated at both the correlated wavefunction and density functional …

Actinide complexes demonstrate unparalleled reactivity towards small molecules. However,
utilizing these powerful transformations in a predictable and deliberate manner remains …

Although the reaction of metallacyclopropenes toward alkyl and aryl nitriles has been
extensively studied, their reactivity toward other types of nitriles, eg, benzyl and benzoyl …

Treatment of the metallacycle [UN* 2 (N, C)][N*= N (SiMe3) 2; N, C= CH2SiMe2N (SiMe3)]
with [HNEt3][BPh4],[HNEt3] Cl, and [pyH][OTf](OTf= OSO2CF3) gave the cationic compound …

Preference for the binding mode of the CN− ligand to Mg (Mg− CN vs. Mg− NC) is
investigated. A monomeric Mg complex with a terminal CN ligand was prepared using the …