Excited (triplet) states offer a myriad of attractive synthetic pathways, including
cycloadditions, selective homolytic bond cleavages and strain-release chemistry …

β-(Hetero) arylethylamines are privileged structural motifs found in many high-value organic
molecules, including pharmaceuticals and natural products. To construct these important …

Sulfur (VI) fluoride exchange (SuFEx) gives rise to a plethora of high-valent sulfur linkages;
however, the availability of (aliphatic) sulfonyl fluoride manifolds lag behind, owing to the …

Highly strained 1, 3-disubstituted bicyclo [1.1. 1] pentanes (BCPs) have been established as
bioisosteres of para-disubstituted benzene because they impart valuable pharmacokinetic …

Radical addition reactions of olefins have emerged as an attractive tool for the rapid
assembly of complex structures, and have plentiful applications in organic synthesis …

Radical remote 1, n-difunctionalization reactions (n> 2) of alkenes are powerful tools to
efficiently introduce functional groups with selected distances into target molecules. Among …

Herein, we disclose a facile and versatile trifluoromethylimination of alkene with a rationally
designed N-(diphenylmethylene)-1, 1, 1-trifluoromethanesulfonamide as a bench-stable and …

Although the direct conversion of gaseous acetylene into value‐added liquid commodity
chemicals is becoming increasingly attractive, the majority of the established methodologies …

A metal-free photosensitized three-component reaction of oxime esters, alkenes, and
DABCO·(SO2) 2 was developed. This protocol could accommodate a wide substrate scope …

In the long-standing quest to synthesize fundamental building blocks with key functional
group motifs, photochemistry in the recent past has comprehensively established its …