Single ion magnets from 3d to 5f: developments and strategies

M Feng, ML Tong - Chemistry–A European Journal, 2018 - Wiley Online Library
Abstract Single‐ion magnets (SIMs), exhibiting slow magnetization relaxation in the absence
of the magnetic field, originate from their single spin‐carrier centre. In pursuit of high …

Radical ligand-containing single-molecule magnets

S Demir, IR Jeon, JR Long, TD Harris - Coordination Chemistry Reviews, 2015 - Elsevier
Single-molecule magnets represent the ultimate size limit for spin-based information storage
and processing; however, such applications require large spin relaxation barriers and …

Molecular single-ion magnets based on lanthanides and actinides: Design considerations and new advances in the context of quantum technologies

SG McAdams, AM Ariciu, AK Kostopoulos… - Coordination Chemistry …, 2017 - Elsevier
Over the past fifteen years or so, the study of f-element single-ion magnets (f-SIMs) has gone
from being a sub-discipline of molecular magnetism to an established field of research in its …

Large magnetic anisotropy in mononuclear metal complexes

S Gómez-Coca, D Aravena, R Morales… - Coordination Chemistry …, 2015 - Elsevier
This review examines mononuclear metal complexes with high magnetic anisotropy and the
theoretical approaches used to rationalize their magnetic properties. Electronic structure …

Mononuclear single-molecule magnets: tailoring the magnetic anisotropy of first-row transition-metal complexes

S Gomez-Coca, E Cremades… - Journal of the …, 2013 - ACS Publications
Magnetic anisotropy is the property that confers to the spin a preferred direction that could
be not aligned with an external magnetic field. Molecules that exhibit a high degree of …

Organometallic single-molecule magnets

RA Layfield - Organometallics, 2014 - ACS Publications
Single-molecule magnets (SMMs) display slow relaxation of the magnetization, purely of
molecular origin, in the absence of an applied magnetic field. This review summarizes the …

The crystal chemistry of uranium carboxylates

T Loiseau, I Mihalcea, N Henry, C Volkringer - Coordination Chemistry …, 2014 - Elsevier
The field of uranium carboxylates has been studied for several decades and an important
library of coordination complexes and network solids is now well defined. It mainly concerns …

Influence of Pyrazolate vs N-Heterocyclic Carbene Ligands on the Slow Magnetic Relaxation of Homoleptic Trischelate Lanthanide(III) and Uranium(III) Complexes

KR Meihaus, SG Minasian, WW Lukens Jr… - Journal of the …, 2014 - ACS Publications
Two isostructural series of trigonal prismatic complexes, M (BpMe) 3 and M (BcMe) 3 (M= Y,
Tb, Dy, Ho, Er, U;[BpMe]−= dihydrobis (methypyrazolyl) borate;[BcMe]−= dihydrobis …

Actinide-based single-molecule magnets

KR Meihaus, JR Long - Dalton Transactions, 2015 - pubs.rsc.org
Actinide single-molecule magnetism has experienced steady growth over the last five years
since the first discovery of slow magnetic relaxation in the mononuclear complex U …

Disentangling intricate web of interrelated notions at the interface between the physical (crystal field) Hamiltonians and the effective (spin) Hamiltonians

C Rudowicz, M Karbowiak - Coordination Chemistry Reviews, 2015 - Elsevier
This review provides a summary of distinct Hamiltonians used to describe magnetic and
spectroscopic properties of paramagnetic and magnetic coordination compounds. Based on …