In the era of organic synthesis, the direct difunctionalization strategies of alkenes and
alkynes are very eminent, which open up an excellent route to introduce two functional …

Transition metal catalysis has contributed immensely to C–C bond formation reactions over
the last few decades, and alkylation is no exception. The superiority of such methodologies …

Presented herein is the first report of enantioselective Au (I)/Au (III) redox catalysis, enabled
by a newly designed hemilabile chiral (P, N)-ligand (ChetPhos). The potential of this concept …

Alkene functionalization with a single-atom catalyst (SAC) which merges homogeneous and
heterogeneous catalysis is a fascinating route to obtain high-value-added molecules …

Herein, we report a gold-catalyzed Heck reaction facilitated by the ligand-enabled Au (I)/Au
(III) redox catalysis. The elementary organometallic steps such as migratory insertion and β …

In the last decade, major advances have been made in homogeneous gold catalysis.
However, AuI/AuIII catalytic cycle remains much less explored due to the reluctance of AuI to …

We describe a AuI complex of a hemi‐labile (C^ N) N‐heterocyclic carbene ligand that is
able to mediate oxidative addition of aryl iodides. Detailed computational and experimental …

A copper-catalyzed remote benzylic C–H functionalization strategy enabling 1, 2-
difunctionalization of alkenes with 2-methylbenzeneamides and nucleophiles, including …

Recovery of precious metals from e-waste was of great economic and environmental
significance. Herein, the spherical covalent organic frameworks (COF-V) were constructed …

1, 2-Difunctionalization of styrenes, adding two distinct functional groups across the C═ C
double bond, has emerged as a powerful tool for enhancing molecular complexity. Herein …