The synthesis, properties and potential applications of cyclic polymers
FM Haque, SM Grayson - Nature Chemistry, 2020 - nature.com
Unlike their more common linear counterparts, cyclic polymers have a ring-like structure and
a lack of chain ends. Because of their topology, cyclic polymers exhibit a unique set of …
a lack of chain ends. Because of their topology, cyclic polymers exhibit a unique set of …
Cyclic polymers: synthesis, characteristics, and emerging applications
Cyclic polymers with a ring-like topology and no chain ends are a unique class of
macromolecules. In the past several decades, significant advances have been made to …
macromolecules. In the past several decades, significant advances have been made to …
Self-nucleation effects on polymer crystallization
The existence of a “memory” of the previous crystalline state, which survives melting and
enhances recrystallization kinetics by a self-nucleation process, is well-known in polymer …
enhances recrystallization kinetics by a self-nucleation process, is well-known in polymer …
Effect of Molecular Weight on the Crystallization and Melt Memory of Poly (ε-caprolactone)(PCL)
A Fernández-Tena, RA Pérez-Camargo… - …, 2023 - ACS Publications
The role of the molecular weight in the crystallization and melt memory of poly (ε-
caprolactone)(PCL) was investigated. To this end, 10 PCL samples of synthetic and …
caprolactone)(PCL) was investigated. To this end, 10 PCL samples of synthetic and …
Cyclic polymers: Advances in their synthesis, properties, and biomedical applications
R Liénard, J De Winter… - Journal of Polymer …, 2020 - Wiley Online Library
Since the time first synthetic macrocycles were observed as academic curiosities, great
advances have been made. Thanks to the development of controlled polymerization …
advances have been made. Thanks to the development of controlled polymerization …
Molecular dynamics simulations of the effects of entanglement on polymer crystal nucleation
We investigate the effects of entanglement on polymer crystallization using atomistic
molecular dynamics simulations of linear and cyclic polyethylene (PE). While linear chains …
molecular dynamics simulations of linear and cyclic polyethylene (PE). While linear chains …
Topology Matters: Conformation and Microscopic Dynamics of Ring Polymers
M Kruteva, J Allgaier, D Richter - Macromolecules, 2023 - ACS Publications
Ring polymers have fascinated theorists, simulators, and experimentalists as they are the
simplest polymer without ends, giving rise to important topology related properties. We …
simplest polymer without ends, giving rise to important topology related properties. We …
Regulation of two-dimensional platelet micelles by dynamic changing of polymer topological architectures upon light irradiation
B Xiang, X Wang, F Teng, L Liu, M Li, X Meng… - …, 2023 - ACS Publications
Utilization of the crystallization-driven self-assembly (CDSA) approach has revolutionized
the production of precisely controlled core–shell nanoparticles. However, the current scope …
the production of precisely controlled core–shell nanoparticles. However, the current scope …
Synthesis, properties, and applications of bio-based cyclic aliphatic polyesters
PB Yang, MG Davidson, KJ Edler, S Brown - Biomacromolecules, 2021 - ACS Publications
Cyclic polymers have long been reported in the literature, but their development has often
been stunted by synthetic difficulties such as the presence of linear contaminants. Research …
been stunted by synthetic difficulties such as the presence of linear contaminants. Research …
Chemical structure drives memory effects in the crystallization of homopolymers
L Sangroniz, A Sangroniz, L Meabe… - …, 2020 - ACS Publications
Although the study of melt memory has attracted much interest, the effect of polymer
chemical structure on its origin has not been fully elucidated. In this work, we study the melt …
chemical structure on its origin has not been fully elucidated. In this work, we study the melt …