IR-induced and tunneling reactions in cryogenic matrices: the (incomplete) story of a successful endeavor
In this article, IR-induced and tunneling-driven reactions observed in cryogenic matrices are
described in a historical perspective, the entangling of the two types of processes being …
described in a historical perspective, the entangling of the two types of processes being …
[HTML][HTML] Genesis of rare molecules using light-induced reactions of matrix-isolated tetrazoles
Tetrazoles exhibit a very rich photochemistry, strongly influenced by the nature of
substituents in the tetrazolic ring. Photolysis of representative tetrazoles trapped in a rigid …
substituents in the tetrazolic ring. Photolysis of representative tetrazoles trapped in a rigid …
Conformational Switching in Pyruvic Acid Isolated in Ar and N2 Matrixes: Spectroscopic Analysis, Anharmonic Simulation, and Tunneling
Monomers of pyruvic acid (PA) isolated in cryogenic argon and nitrogen matrixes were
characterized by mid-and near-infrared spectroscopy. Interpretation of the experiments was …
characterized by mid-and near-infrared spectroscopy. Interpretation of the experiments was …
Capture of an elusive nitrile ylide as an Intermediate in isoxazole–oxazole photoisomerization
The unimolecular photochemistry of 3, 5-dimethylisoxazole (1) induced by a narrow-band
tunable UV laser was studied using low-temperature matrix isolation coupled with infrared …
tunable UV laser was studied using low-temperature matrix isolation coupled with infrared …
Effects of entangled IR radiation and tunneling on the conformational interconversion of 2-cyanophenol
The conformers of 2-cyanophenol (2CP) and their interconversions were studied by infrared
(IR) spectroscopy after trapping the monomers of the gaseous compound into low …
(IR) spectroscopy after trapping the monomers of the gaseous compound into low …
Near-infrared laser induced conformational change of alanine in low-temperature matrixes and the tunneling lifetime of its conformer VI
G Bazsó, EE Najbauer, G Magyarfalvi… - The Journal of Physical …, 2013 - ACS Publications
The near-and mid-IR spectra of α-alanine isolated in low-temperature Ar, Kr, and N2
matrixes were measured. Production of the short-lived conformer VI at the expense of the …
matrixes were measured. Production of the short-lived conformer VI at the expense of the …
Spontaneous tunneling and near-infrared-induced interconversion between the amino-hydroxy conformers of cytosine
Spontaneous and near-infrared/infrared (NIR/IR)-induced interconversions between two
amino-hydroxy conformers of monomeric cytosine have been investigated for the compound …
amino-hydroxy conformers of monomeric cytosine have been investigated for the compound …
Matrix-isolation vibrational circular dichroism (VCD) spectroscopy of chiral 1-phenyl-1-propanol
C Grassin, C Merten - Physical Chemistry Chemical Physics, 2023 - pubs.rsc.org
Matrix Isolation IR and VCD spectroscopy is used to characterize the self-aggregation of the
title compound. It is shown that only the IR spectral region of the OH-/CH-stretching modes is …
title compound. It is shown that only the IR spectral region of the OH-/CH-stretching modes is …
Identification of serine conformers by matrix-isolation IR spectroscopy aided by near-infrared laser-induced conformational change, 2D correlation analysis, and …
EE Najbauer, G Bazso, R Apostolo… - The Journal of …, 2015 - ACS Publications
The conformers of α-serine were investigated by matrix-isolation IR spectroscopy combined
with NIR laser irradiation. This method, aided by 2D correlation analysis, enabled …
with NIR laser irradiation. This method, aided by 2D correlation analysis, enabled …
Direct observation of tunnelling reactions by matrix isolation spectroscopy
The theoretical foundations for nuclei and electron tunnelling were put forward by Hund, 1
Wigner, 2 Bell, 3 and others, 4, 5 following the establishment of quantum mechanics. A more …
Wigner, 2 Bell, 3 and others, 4, 5 following the establishment of quantum mechanics. A more …