Asymmetric allylic alkylation mediated by transition metals provides an efficient strategy to
form quaternary stereogenic centers. While this transformation is dominated by the use of …

Complexes of metals with N-heterocyclic carbene ligands (M/NHC) are typically considered
the systems of choice in homogeneous catalysis due to their stable metal–ligand framework …

Asymmetric metal based catalysis has advanced quickly in recent years, with its efficiency
relying exclusively on chiral ligands. Rational design and meticulous selection of chiral …

The utility of carbazole in photo-, electro-, and medicinal applications has ensured its
widespread use also as the backbone in tridentate pincer ligands. In this review, the aim is …

Since the discovery of persistent carbenes by the isolation of 1, 3-di-l-adamantylimidazol-2-
ylidene by Arduengo and coworkers, we witnessed a fast growth in the design and …

By using copper (I) homoenolates as nucleophiles, which are generated through the ring‐
opening of 1‐substituted cyclopropane‐1‐ols, a catalytic asymmetric allylic substitution with …

Porous organometallic polymers (POMPs) with hierarchical pore structures, high specific
surface areas, and atomically dispersed metal (Ir, Pd, Ru) centers are successfully fabricated …

A neutral azole precursor to a protic N-heterocyclic carbene (p NHC) ligand, 6-((4, 5-
diphenyl-1 H-imidazol-1-yl) methyl)-2, 2′-bipyridine (3), was prepared from 6 …

与广泛使用的聚烯烃材料相比, 脂肪族聚酯由于其独特的生物相容性和可降解性, 在电子,
包装和生物医学等领域都有广泛的应用. 开环聚合(ROP) 是目前合成脂肪族聚酯的主要方法 …

N‐Heterocyclic carbenes (NHCs) have become immensely successful ligands in
coordination chemistry and homogeneous catalysis due to their strong terminal σ‐donor …