Vicinal diamines are a common structural motif in bioactive natural products, therapeutic
agents, and molecular catalysts, motivating the continuing development of efficient …

Unprotected, primary 2-azidoamines are versatile precursors to vicinal diamines, which are
among the most common motifs in biologically active compounds. Herein, we report their …

Diamines are essential building blocks for the synthesis of agrochemicals, drugs, and
organic materials, yet their synthesis remains challenging, as both nitrogens need to be …

Hydrogen sulfide (H 2 S) was discovered as a third gasotransmitter in biological systems
and recent years have seen a growing interest to understand its physiological and …

The implementation of heterogeneous catalysts in advanced organic synthesis provides
basis for the sustainable and cost-effective preparation of pharmaceuticals, agrochemicals …

In this work, a single‐atom cobalt‐catalyzed transfer hydrogenation (TH) of azides is
reported under mild conditions (at 30° C in 30 min) using NH2NH2⋅ H2O as the hydrogen …

A convenient and efficient manganese‐catalyzed trifluoromethylazidation of alkenes has
been developed by utilizing inexpensive and readily available CF3SO2Na under mild …

A unique self-detachable protecting group function of CO2 in the selective electrochemical
reduction of azides is reported. By utilizing CO2 as the self-detachable protecting group, the …

Organic azides are still in the center of click chemistry connecting two molecules. However,
taming the conjugation selectivity of azides is difficult without the help of bulky groups. We …

The use of chiral ligands to tune the reactivity and enantioselectivity of transition‐metal
catalyst for asymmetric transformations is a central challenge in synthetic organic chemistry …