Advances in synthetic applications of hypervalent iodine compounds

A Yoshimura, VV Zhdankin - Chemical reviews, 2016 - ACS Publications
The preparation, structure, and chemistry of hypervalent iodine compounds are reviewed
with emphasis on their synthetic application. Compounds of iodine possess reactivity similar …

Iodine (V)-Based Oxidants in Oxidation Reactions

SE Shetgaonkar, S Jothish, T Dohi, FV Singh - Molecules, 2023 - mdpi.com
The chemistry of hypervalent iodine reagents has now become quite valuable due to the
reactivity of these compounds under mild reaction conditions and their resemblance in …

Bis (methoxypropyl) ether-promoted oxidation of aromatic alcohols into aromatic carboxylic acids and aromatic ketones with O 2 under metal-and base-free conditions

KJ Liu, S Jiang, LH Lu, LL Tang, SS Tang, HS Tang… - Green …, 2018 - pubs.rsc.org
We describe an eco-friendly, practical and operationally simple procedure for the bis
(methoxypropyl) ether-promoted oxidation of aromatic alcohols into aromatic carboxylic …

Oxidative cleavage of olefins by in situ-generated catalytic 3, 4, 5, 6-tetramethyl-2-iodoxybenzoic acid/oxone

JN Moorthy, KN Parida - The Journal of Organic Chemistry, 2014 - ACS Publications
Oxidative cleavage of a variety of olefins to the corresponding ketones/carboxylic acids is
shown to occur in a facile manner with 3, 4, 5, 6-tetramethyl-2-iodobenzoic acid (TetMe …

Visible Light-Induced Decomposition of Acyl Peroxides Using Isocyanides: Synthesis of Heteroarenes by Radical Cascade Cyclization

N Yadav, SR Bhatta, JN Moorthy - The Journal of Organic …, 2023 - ACS Publications
Visible light-mediated facile synthesis of heteroarenes, namely, isoquinolines,
benzothiazoles, and quinazolines, is demonstrated by employing isocyanides and …

λ3‐ and λ5‐Iodanes: Substituent Effects and Pseudorotation/Hypervalent Twisting

KN Parida, JN Moorthy - Chemistry–A European Journal, 2023 - Wiley Online Library
Hypervalent iodine (III and V) compounds exhibit positional isomerization through
pseudorotation or twisting; the latter have been invoked for the stability as well as the …

Bimetallic oxide catalyst for the dehydrogenative oxidation reaction of alcohols: practical application in the synthesis of value-added chemicals

R Mittal, SK Awasthi - ACS Sustainable Chemistry & Engineering, 2022 - ACS Publications
This work demonstrates the preparation of zinc cobalt oxide materials (ZCO-1, ZCO-2, and
ZCO-3) via thermal annealing of novel zinc cobalt acetate hydroxide precursors prepared in …

Aqueous mediated reactions involving hypervalent iodine reagents

R Soni, M Sihag, N Rani, M Kinger… - Asian Journal of …, 2022 - Wiley Online Library
Several reactions mended by hypervalent iodine reagents have been developed in aqueous
media recently. The evolution of reactions using hypervalent iodine reagents in aqueous …

Mechanochemical catalytic oxidations in the solid state with in situ-generated modified IBX from 3, 5-di-tert-butyl-2-iodobenzoic acid (DTB-IA)/Oxone

AK Mishra, JN Moorthy - Organic Chemistry Frontiers, 2017 - pubs.rsc.org
IBX is an indispensable reagent in contemporary organic oxidation chemistry, despite its
explosive and insoluble attributes. The latter drawbacks can be overcome if a more reactive …

Oxidation cascade with oxone: cleavage of olefins to carboxylic acids

KN Parida, JN Moorthy - Tetrahedron, 2014 - Elsevier
A variety of olefins is shown to be cleaved oxidatively to the corresponding acids with oxone
as the reagent. The simple methodology that works well for a range of alkenes, ie, styrenes …