This review systematizes data on the coordination ability of mono-and disubstituted
derivatives of boron cluster anions and carboranes in complexation with transition metals …

Here, we present composites and materials that can be prepared starting with boron hydride
cluster compounds (decaborane, decahydro-closo-decaborate and dodecahydro-closo …

The review covers more than a century of decaborane chemistry from the first synthesis by
Alfred Stock to the present day. The main attention is paid to the reactions of the substitution …

A potentially general intermediate,[closo-B10H8-10-PhI-1-COOH]–, for a class of functional
anionic carboxylic acids,[closo-B10H8-10-X-1-COOH] 2–, was obtained in four steps and …

The preparation of novel nitrilium derivatives of closo-dodecaborate anion [B12H11NCR]−,
R= n-C3H7, i-C3H7, 4-C6H4CH3, 1-C10H7 is described. Target compounds were obtained …

In this work, we studied lead (II) and cobalt (II) complexation of derivatives [2-B10H9O (CH2)
2O (CH2) 2N3] 2− and [2-B10H9O (CH2) 5N3] 2− of the closo-decaborate anion containing …

Herein we report the synthesis of a new class of compounds associating Keggin and
Dawson-type Polyoxometalates (POMs) with a derivative of the anionic decahydro-closo …

Mixed-ligand lead (II) complexes with 2, 2′-bipyridyl and [B10H9OH] 2− or monosubstituted
hydroxy-substituted closo-decaborate anions with a pendant hydroxy group, separated from …

A new class of rigid, photoactive heteroditopic anionic ligands based on the 1, 10-
disubstituted [closo-B10H10] 2–anion was designed and six of these compounds were …

A comprehensive study focused on the preparation of disubstituted carboxonium derivatives
of closo-decaborate anion [2, 6-B10H8O2CC6H5]− was carried out. The proposed synthesis …