Reductive amination/cyclization of keto acids using a hydrosilane for selective production of lactams versus cyclic amines by switching of the indium catalyst
Y Ogiwara, T Uchiyama, N Sakai - Angewandte Chemie, 2016 - Wiley Online Library
Described herein is that the catalytic construction of N‐substituted five‐and six‐membered
lactams from keto acids with primary amines by reductive amination, using an indium/silane …
lactams from keto acids with primary amines by reductive amination, using an indium/silane …
Tetramethyldisiloxane: a practical organosilane reducing agent
J Pesti, GL Larson - Organic Process Research & Development, 2016 - ACS Publications
The chemistry of tetramethyldisiloxane (TMDS) is largely composed of the reduction of
functional groups with increasing applications for carbon–carbon bond formation. This …
functional groups with increasing applications for carbon–carbon bond formation. This …
Chemoselective reduction of tertiary amides under thermal control: formation of either aldehydes or amines
F Tinnis, A Volkov, T Slagbrand… - Angewandte …, 2016 - Wiley Online Library
The chemoselective reduction of amides in the presence of other more reactive reducible
functional groups is a highly challenging transformation, and successful examples thereof …
functional groups is a highly challenging transformation, and successful examples thereof …
pH-Mediated Selective Synthesis of N-Allylic Alkylation or N-Alkylation Amines with Allylic Alcohols via an Iridium Catalyst in Water
N Luo, Y Zhong, H Shui, R Luo - The Journal of Organic …, 2021 - ACS Publications
Amination of allylic alcohols is an effective approach in the facile synthesis of N-allylic
alkylation or N-alkylation amines. Recently, a series of catalysts were devised to push …
alkylation or N-alkylation amines. Recently, a series of catalysts were devised to push …
Mild metal-free hydrosilylation of secondary amides to amines
PQ Huang, QW Lang, YR Wang - The Journal of Organic …, 2016 - ACS Publications
The combination of amide activation by Tf2O with B (C6F5) 3-catalyzed hydrosilylation with
TMDS constitutes a method for the one-pot reduction of secondary amides to amines under …
TMDS constitutes a method for the one-pot reduction of secondary amides to amines under …
Deoxygenative hydrogenation of amides catalyzed by a well-defined iridium pincer complex
ML Yuan, JH Xie, SF Zhu, QL Zhou - ACS Catalysis, 2016 - ACS Publications
The iridium-catalyzed highly chemoselective hydrogenation of amides to amines has been
developed. Using a well-defined iridium catalyst bearing a P (O) C (O) P pincer ligand …
developed. Using a well-defined iridium catalyst bearing a P (O) C (O) P pincer ligand …
Borinic acid catalysed reduction of tertiary amides with hydrosilanes: a mild and chemoselective synthesis of amines
A Chardon, T Mohy El Dine, R Legay… - … A European Journal, 2017 - Wiley Online Library
A reduction of various aryl, alkyl, and α, β‐unsaturated amides with phenylsilane, catalysed
by a borinic acid, is reported. The unprecedented reaction was carried out under very mild …
by a borinic acid, is reported. The unprecedented reaction was carried out under very mild …
Formal Deoxygenative Hydrogenation of Lactams Using PNHP-Pincer Ruthenium Complexes under Nonacidic Conditions
O Ogata, H Nara, K Matsumura, Y Kayaki - Organic letters, 2019 - ACS Publications
A formal deoxygenative hydrogenation of amides to amines with RuCl2
(NHC)(PNHP)(NHC= 1, 3-dimethylimizadol-2-ylidene, PNHP= bis (2 …
(NHC)(PNHP)(NHC= 1, 3-dimethylimizadol-2-ylidene, PNHP= bis (2 …
Hydroxy group directed catalytic hydrosilylation of amides
J Ni, T Oguro, T Sawazaki, Y Sohma, M Kanai - Organic Letters, 2018 - ACS Publications
Chemo-and site-selective hydrosilylation of α-or β-hydroxy amides using organocatalyst B
(C6F5) 3 and commercially available hydrosilanes is described. This transformation is …
(C6F5) 3 and commercially available hydrosilanes is described. This transformation is …
Indium-catalyzed direct conversion of lactones into thiolactones and selenolactones in the presence of elemental sulfur and selenium
N Sakai, S Horikawa, Y Ogiwara - Synthesis, 2018 - thieme-connect.com
Thieme E-Journals - Synthesis / Full Text DE EN Home Products Journals Books Book Series
Service Library Service Help Contact Portal SYNTHESIS Full-text search Full-text search Author …
Service Library Service Help Contact Portal SYNTHESIS Full-text search Full-text search Author …