Described herein is that the catalytic construction of N‐substituted five‐and six‐membered
lactams from keto acids with primary amines by reductive amination, using an indium/silane …

The chemistry of tetramethyldisiloxane (TMDS) is largely composed of the reduction of
functional groups with increasing applications for carbon–carbon bond formation. This …

The chemoselective reduction of amides in the presence of other more reactive reducible
functional groups is a highly challenging transformation, and successful examples thereof …

Amination of allylic alcohols is an effective approach in the facile synthesis of N-allylic
alkylation or N-alkylation amines. Recently, a series of catalysts were devised to push …

The combination of amide activation by Tf2O with B (C6F5) 3-catalyzed hydrosilylation with
TMDS constitutes a method for the one-pot reduction of secondary amides to amines under …

The iridium-catalyzed highly chemoselective hydrogenation of amides to amines has been
developed. Using a well-defined iridium catalyst bearing a P (O) C (O) P pincer ligand …

A reduction of various aryl, alkyl, and α, β‐unsaturated amides with phenylsilane, catalysed
by a borinic acid, is reported. The unprecedented reaction was carried out under very mild …

A formal deoxygenative hydrogenation of amides to amines with RuCl2
(NHC)(PNHP)(NHC= 1, 3-dimethylimizadol-2-ylidene, PNHP= bis (2 …

Chemo-and site-selective hydrosilylation of α-or β-hydroxy amides using organocatalyst B
(C6F5) 3 and commercially available hydrosilanes is described. This transformation is …

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