Semiconductor nanocrystals for small molecule activation via artificial photosynthesis
XB Li, ZK Xin, SG Xia, XY Gao, CH Tung… - Chemical Society …, 2020 - pubs.rsc.org
Facile activation and conversion of small molecules (eg, H2O, CO2, N2, CH4, and C6H6)
into solar fuels or value-added chemicals under mild conditions is an attractive pathway in …
into solar fuels or value-added chemicals under mild conditions is an attractive pathway in …
Synergy between metals for small molecule activation: Enzymes and bio-inspired complexes
AC Ghosh, C Duboc, M Gennari - Coordination Chemistry Reviews, 2021 - Elsevier
Transition metal-driven small molecule activation is essential for the production of fuels and
chemicals or energy supply. The use of multimetallic catalysts, where two or more metal …
chemicals or energy supply. The use of multimetallic catalysts, where two or more metal …
Ligand Redox Activity of Organonickel Radical Complexes Governed by the Geometry
Nickel-catalyzed cross-coupling reactions often employ bidentate π-acceptor N-ligands to
facilitate radical pathways. This report presents the synthesis and characterization of a …
facilitate radical pathways. This report presents the synthesis and characterization of a …
Complexes of Ni (I): a “rare” oxidation state of growing importance
Nickel plays an important role in areas as diverse as metallurgy, magnetism and biology as
well as in chemical applications such as the catalytic transformation of organic substrates …
well as in chemical applications such as the catalytic transformation of organic substrates …
Mechanistic characterization of (xantphos) Ni (I)-mediated alkyl bromide activation: oxidative addition, electron transfer, or halogen-atom abstraction
JB Diccianni, J Katigbak, C Hu… - Journal of the American …, 2019 - ACS Publications
Ni (I)-mediated single-electron oxidative activation of alkyl halides has been extensively
proposed as a key step in Ni-catalyzed cross-coupling reactions to generate radical …
proposed as a key step in Ni-catalyzed cross-coupling reactions to generate radical …
Electrochemically induced nickel catalysis for oxygenation reactions with water
Nickel has been found in some metalloproteins that execute catalytic aerobic oxygenation
reactions in which nickel–dioxygen species are proposed as the key catalytic species. Thus …
reactions in which nickel–dioxygen species are proposed as the key catalytic species. Thus …
A Bimetallic Nickel–Gallium Complex Catalyzes CO2 Hydrogenation via the Intermediacy of an Anionic d10 Nickel Hydride
Large-scale CO2 hydrogenation could offer a renewable stream of industrially important C1
chemicals while reducing CO2 emissions. Critical to this opportunity is the requirement for …
chemicals while reducing CO2 emissions. Critical to this opportunity is the requirement for …
Reactivity of (bi-Oxazoline) organonickel Complexes and Revision of a Catalytic Mechanism
Bi-Oxazoline (biOx) has emerged as an effective ligand framework for promoting nickel-
catalyzed cross-coupling, cross-electrophile coupling, and photoredox-nickel dual catalytic …
catalyzed cross-coupling, cross-electrophile coupling, and photoredox-nickel dual catalytic …
Ni (I)–X complexes bearing a bulky α-diimine ligand: synthesis, structure, and superior catalytic performance in the hydrogen isotope exchange in pharmaceuticals
The synthesis and spectroscopic characterization of a family of Ni–X (X= Cl, Br, I, H)
complexes supported by the bulky α-diimine chelate N, N′-bis (1 R, 2 R, 3 R, 5 S)-(−) …
complexes supported by the bulky α-diimine chelate N, N′-bis (1 R, 2 R, 3 R, 5 S)-(−) …
Redox activity of pyridine-oxazoline ligands in the stabilization of low-valent organonickel radical complexes
Low-valent organonickel radical complexes are common intermediates in cross-coupling
reactions and metalloenzyme-mediated processes. The electronic structures of N-ligand …
reactions and metalloenzyme-mediated processes. The electronic structures of N-ligand …