Atom transfer radical polymerization: a mechanistic perspective

F Lorandi, M Fantin… - Journal of the American …, 2022 - ACS Publications
Since its inception, atom transfer radical polymerization (ATRP) has seen continuous
evolution in terms of the design of the catalyst and reaction conditions; today, it is one of the …

Advanced materials by atom transfer radical polymerization

K Matyjaszewski - Advanced Materials, 2018 - Wiley Online Library
Atom transfer radical polymerization (ATRP) has been successfully employed for the
preparation of various advanced materials with controlled architecture. New catalysts with …

Externally controlled atom transfer radical polymerization

X Pan, M Fantin, F Yuan, K Matyjaszewski - Chemical Society Reviews, 2018 - pubs.rsc.org
Spatial and temporal regulations of ATRP by external stimuli are presented. Various ATRP
techniques, eATRP, photoATRP, and mechanoATRP, are controlled by electrical current …

Macromolecular engineering by atom transfer radical polymerization

K Matyjaszewski, NV Tsarevsky - Journal of the American …, 2014 - ACS Publications
This Perspective presents recent advances in macromolecular engineering enabled by
ATRP. They include the fundamental mechanistic and synthetic features of ATRP with …

Electrochemically mediated atom transfer radical polymerization (eATRP)

P Chmielarz, M Fantin, S Park, AA Isse… - Progress in Polymer …, 2017 - Elsevier
This review covers both fundamental aspects and applications of electrochemically
mediated atom transfer radical polymerization (eATRP). eATRP setup is discussed in detail …

Advances in polymerizations modulated by external stimuli

AM Doerr, JM Burroughs, SR Gitter, X Yang… - ACS …, 2020 - ACS Publications
Synthetic polymer chemistry endeavors to imitate the spatial and temporal control exhibited
within biological systems to obtain well-defined polymeric materials with unique structures …

The scale-up of electrochemically mediated atom transfer radical polymerization without deoxygenation

F De Bon, RG Fonseca, F Lorandi, AC Serra… - Chemical Engineering …, 2022 - Elsevier
The scale-up of Atom Transfer Radical Polymerization (ATRP) from 15 mL to 15 L (scale-up
factor 1000) by galvanostatic simplified electrochemically mediated ATRP (seATRP) is …

Electrochemically controlled cationic polymerization of vinyl ethers

BM Peterson, S Lin, BP Fors - Journal of the American Chemical …, 2018 - ACS Publications
Control of polymer initiation, propagation and termination is important in the development of
complex polymer structures and advanced materials. Typically, this has been achieved …

Preparation of well-defined polymers and DNA–polymer bioconjugates via small-volume eATRP in the presence of air

Y Sun, S Lathwal, Y Wang, L Fu, M Olszewski… - ACS Macro …, 2019 - ACS Publications
An aqueous electrochemically mediated atom transfer radical polymerization (eATRP) was
performed in a small volume solution (75 μL) deposited on a screen-printed electrode (SPE) …

Harnessing the Interaction between Surfactant and Hydrophilic Catalyst To Control eATRP in Miniemulsion

M Fantin, P Chmielarz, Y Wang, F Lorandi… - …, 2017 - ACS Publications
In an electrochemically mediated atom transfer radical polymerization (eATRP, Scheme 1)
the active CuI catalyst is (re) generated by electrochemical reduction at a working electrode …