Rational Assembly of High‐Spin Polynuclear Magnetic Complexes into Coordination Networks: the Case of a [Mn4] Single‐Molecule Magnet Building Block

O Roubeau, R Clérac - European Journal of Inorganic …, 2008 - Wiley Online Library
The synthesis of transition‐metal high‐spin complexes and of infinite coordination networks
of these high‐spin carriers now represents a recognized subdiscipline of coordination …

Recent advances in coordination chemistry of metal complexes based on nitrogen heteroaromatic alcohols. Synthesis, structures and potential applications

J Masternak, M Zienkiewicz-Machnik, M Kowalik… - Coordination Chemistry …, 2016 - Elsevier
This review is focused on the use of nitrogen-containing heteroaromatic alcohols as ligands
with increasing significance in diverse areas of chemistry. The application of such ligands …

Structure, Magnetism and Theory of a Family of Nonanuclear CuII5LnIII4–Triethanolamine Clusters Displaying Single‐Molecule Magnet Behaviour

SK Langley, L Ungur, NF Chilton… - … A European Journal, 2011 - Wiley Online Library
Synthesis, crystal structures and magnetic studies are reported for four new heterometallic
CuII–LnIII clusters. The reaction of Cu (NO3) 2⋅ 3H2O with triethanolamine (teaH3), pivalic …

Heterometallic cubanes: syntheses, structures, and magnetic properties of lanthanide (III)− nickel (II) architectures

Y Gao, L Zhao, X Xu, GF Xu, YN Guo, J Tang… - Inorganic …, 2011 - ACS Publications
Reactions of lanthanide (III) perchlorate (Ln= Dy, Tb, and Gd), nickel (II) acetate, and ditopic
ligand 2-(benzothiazol-2-ylhydrazonomethyl)-6-methoxyphenol (H2L) in a mixture of …

A new family of 1D exchange biased heterometal single-molecule magnets: observation of pronounced quantum tunneling steps in the hysteresis loops of quasi-linear …

A Das, K Gieb, Y Krupskaya, S Demeshko… - Journal of the …, 2011 - ACS Publications
First members of a new family of heterometallic Mn/Ni complexes [Mn2Ni3X2L4 (LH) 2
(H2O) 2](X= Cl: 1; X= Br: 2) with the new ligand 2-{3-(2-hydroxyphenyl)-1 H-pyrazol-1-yl} …

Two-dimensional networks of lanthanide cubane-shaped dumbbells

D Savard, PH Lin, TJ Burchell, I Korobkov… - Inorganic …, 2009 - ACS Publications
The syntheses, structures, and magnetic properties are reported for three new lanthanide
complexes,[LnIII4 (μ3− OH) 2 (μ3− O) 2 (cpt) 6 (MeOH) 6 (H2O)] 2 (Ln= Dy (1· 15MeOH), Ho …

Carboxylate-Free MnIII2LnIII2 (Ln = Lanthanide) and MnIII2YIII2 Complexes from the Use of (2-Hydroxymethyl)pyridine: Analysis of Spin Frustration Effects

C Papatriantafyllopoulou, KA Abboud… - Inorganic …, 2011 - ACS Publications
The initial employment of 2-(hydroxymethyl) pyridine for the synthesis of Mn/Ln (Ln=
lanthanide) and Mn/Y clusters, in the absence of an ancillary organic ligand, has afforded a …

Ubiquity of cubanes in bioinorganic relevant compounds

A Bigness, S Vaddypally, MJ Zdilla… - Coordination Chemistry …, 2022 - Elsevier
The heterocubane (commonly referred to as the cubane cluster, a molecular species
comprising a cube-shaped core with different atom types at opposite corners) is a conserved …

High-frequency and-field electron paramagnetic resonance of transition metal ion (d block) coordination complexes

J Telser, A Ozarowski, J Krzystek - Electron Paramagnetic …, 2012 - books.google.com
High-frequency and-field electron paramagnetic resonance (HFEPR), in its current
configuration (frequencies up to 1THz; fields up to 35T), has been applied to transition metal …

Molecular spin valve and spin filter composed of single-molecule magnets

L Zhu, KL Yao, ZL Liu - Applied Physics Letters, 2010 - pubs.aip.org
We presented a theoretical study on the spin-polarized transport of one single-molecule
magnet. The results show it has spin filter behavior, and can also be used as a molecular …