Spin hyperpolarization in modern magnetic resonance

J Eills, D Budker, S Cavagnero, EY Chekmenev… - Chemical …, 2023 - ACS Publications
Magnetic resonance techniques are successfully utilized in a broad range of scientific
disciplines and in various practical applications, with medical magnetic resonance imaging …

Primary structure of glycans by NMR spectroscopy

C Fontana, G Widmalm - Chemical Reviews, 2023 - ACS Publications
Glycans, carbohydrate molecules in the realm of biology, are present as biomedically
important glycoconjugates and a characteristic aspect is that their structures in many …

Dynamic nuclear polarization for sensitivity enhancement in biomolecular solid-state NMR

T Biedenbänder, V Aladin, S Saeidpour… - Chemical …, 2022 - ACS Publications
Solid-state NMR with magic-angle spinning (MAS) is an important method in structural
biology. While NMR can provide invaluable information about local geometry on an atomic …

SHARPER-DOSY: Sensitivity enhanced diffusion-ordered NMR spectroscopy

G Peat, PJ Boaler, CL Dickson, GC Lloyd-Jones… - Nature …, 2023 - nature.com
Since its discovery in mid-20th century, the sensitivity of Nuclear Magnetic Resonance
(NMR) has increased steadily, in part due to the design of new, sophisticated NMR …

Overhauser enhanced liquid state nuclear magnetic resonance spectroscopy in one and two dimensions

M Levien, L Yang, A van der Ham, M Reinhard… - Nature …, 2024 - nature.com
Nuclear magnetic resonance (NMR) is fundamental in the natural sciences, from chemical
analysis and structural biology, to medicine and physics. Despite its enormous …

NMR methods for the analysis of mixtures

JN Dumez - Chemical Communications, 2022 - pubs.rsc.org
NMR spectroscopy is a powerful approach for the analysis of mixtures. Its usefulness arises
in large part from the vast landscape of methods, and corresponding pulse sequences, that …

Polarizing agents beyond pentacene for efficient triplet dynamic nuclear polarization in glass matrices

K Sakamoto, T Hamachi, K Miyokawa… - Proceedings of the …, 2023 - National Acad Sciences
Triplet dynamic nuclear polarization (triplet-DNP) is a technique that can obtain high nuclear
polarization under moderate conditions. However, in order to obtain practically useful …

Glycan Shape, Motions, and Interactions Explored by NMR Spectroscopy

G Widmalm - JACS Au, 2024 - ACS Publications
Glycans in the form of oligosaccharides, polysaccharides, and glycoconjugates are
ubiquitous in nature, and their structures range from linear assemblies to highly branched …

Proton hyperpolarization relay from nanocrystals to liquid water

N Matsumoto, K Nishimura, N Kimizuka… - Journal of the …, 2022 - ACS Publications
Dynamic nuclear polarization (DNP) using transient electron spin polarization generated by
photoexcitation can improve nuclear magnetic resonance (NMR) sensitivity far beyond the …

1H Hyperpolarization of Solutions by Overhauser Dynamic Nuclear Polarization with 13C–1H Polarization Transfer

Y Rao, A Venkatesh, P Moutzouri… - The Journal of Physical …, 2022 - ACS Publications
Dynamic nuclear polarization (DNP) is a method that can significantly increase the
sensitivity of nuclear magnetic resonance. The only effective DNP mechanism for in situ …