Diboron (4) compounds: from structural curiosity to synthetic workhorse

EC Neeve, SJ Geier, IAI Mkhalid, SA Westcott… - Chemical …, 2016 - ACS Publications
Although known for over 90 years, only in the past two decades has the chemistry of diboron
(4) compounds been extensively explored. Many interesting structural features and reaction …

A copper-mediated oxidative N-cyanation reaction

F Teng, JT Yu, Y Jiang, H Yang, J Cheng - Chemical Communications, 2014 - pubs.rsc.org
Copper-promoted N-cyanation of aliphatic sec-amine by CuCN is achieved via oxidative
coupling. This procedure employs O2 as a clean oxidant. Notably, sulfoximines and 1, 1, 3, 3 …

Differential formation of nitrogen-centered radicals leading to unprecedented, regioselective bromination of N, N′-(1, 2-phenylene) bisamides and 2-amidophenols

DR Motati, D Uredi, AG Burra, JP Bowen… - Organic Chemistry …, 2020 - pubs.rsc.org
A highly efficient, site-selective, visible light-accelerated, remote C–H halogenation of
unsymmetrical aromatic bisamides/amidoesters has been developed. Unprecedented …

[PDF][PDF] NH-functionalization of sulfoximines by using hypervalent iodine reagents

C Wang - 2021 - publications.rwth-aachen.de
Sulfoximines 2, the mono aza-analogues of sulfones 1, have found applications as chiral
auxiliaries or ligands in asymmetric organic synthesis [1-3] and organocatalysis.[4] They …