Carbohydrate-based macromolecular biomaterials

L Su, Y Feng, K Wei, X Xu, R Liu, G Chen - Chemical Reviews, 2021 - ACS Publications
Carbohydrates are the most abundant and one of the most important biomacromolecules in
Nature. Except for energy-related compounds, carbohydrates can be roughly divided into …

Supramolecular polymerization through kinetic pathway control and living chain growth

M Wehner, F Würthner - Nature Reviews Chemistry, 2020 - nature.com
Supramolecular polymers exhibit fascinating structures, and their properties, and thus
applications, depend both on the strength and dynamics of the non-covalent bonds and on …

Supramolecular polymorphism in one-dimensional self-assembly by kinetic pathway control

M Wehner, MIS Röhr, M Bühler… - Journal of the …, 2019 - ACS Publications
Controlling polymorphism in molecular solids is of great interest since the properties and
performances of molecular materials depend on the molecules' mutual packing …

Pathway and length control of supramolecular polymers in aqueous media via a hydrogen bonding lock

I Helmers, G Ghosh, RQ Albuquerque… - Angewandte Chemie …, 2021 - Wiley Online Library
Programming the organization of π‐conjugated systems into nanostructures of defined
dimensions is a requirement for the preparation of functional materials. Herein, we have …

Defects and defect engineering in Soft Matter

A Jangizehi, F Schmid, P Besenius, K Kremer… - Soft Matter, 2020 - pubs.rsc.org
Soft matter covers a wide range of materials based on linear or branched polymers, gels and
rubbers, amphiphilic (macro) molecules, colloids, and self-assembled structures. These …

Polymorphism in Squaraine Dye Aggregates by Self‐Assembly Pathway Differentiation: Panchromatic Tubular Dye Nanorods versus J‐Aggregate Nanosheets

CA Shen, D Bialas, M Hecht, V Stepanenko… - Angewandte …, 2021 - Wiley Online Library
A bis (squaraine) dye equipped with alkyl and oligoethyleneglycol chains was synthesized
by connecting two dicyanomethylene substituted squaraine dyes with a phenylene spacer …

Supramolecular double-stranded Archimedean spirals and concentric toroids

N Sasaki, MFJ Mabesoone, J Kikkawa, T Fukui… - Nature …, 2020 - nature.com
Connecting molecular-level phenomena to larger scales and, ultimately, to sophisticated
molecular systems that resemble living systems remains a considerable challenge in …

Diarylethene-powered light-induced folding of supramolecular polymers

T Fukushima, K Tamaki, A Isobe, T Hirose… - Journal of the …, 2021 - ACS Publications
Helical folding of randomly coiled linear polymers is an essential organization process not
only for biological polypeptides but also for synthetic functional polymers. Realization of this …

Unraveling concomitant packing polymorphism in metallosupramolecular polymers

A Langenstroer, KK Kartha, Y Dorca… - Journal of the …, 2019 - ACS Publications
The phenomenon of polymorphism is ubiquitous in biological systems and has also been
observed in various types of self-assembled materials in solution and in the solid state. In …

Thermoreversible Polymorph Transitions in Supramolecular Polymers of Hydrogen‐Bonded Squaramides

S Bujosa, A Doncel‐Giménez, N Bäumer… - Angewandte Chemie …, 2022 - Wiley Online Library
Hydrogen‐bonded squaramide (SQ) supramolecular polymers exhibit uncommon
thermoreversible polymorph transitions between particle‐and fiber‐like nanostructures. SQs …