Bimetallic cooperation across the periodic table

J Campos - Nature Reviews Chemistry, 2020 - nature.com
Organometallic chemistry and its applications in homogeneous catalysis have been
dominated by mononuclear transition-metal complexes. The catalytic performance and …

Molecular anions perspective

J Simons - The Journal of Physical Chemistry A, 2023 - ACS Publications
This Perspective attempts to shed light on developments in the theoretical and experimental
study of molecular anions highlighting more recent workers in the field. The species I …

Operando Mössbauer Spectroscopic Tracking the Metastable State of Atomically Dispersed Tin in Copper Oxide for Selective CO2 Electroreduction

R Chen, J Zhao, Y Li, Y Cui, YR Lu… - Journal of the …, 2023 - ACS Publications
Metastable state is the most active catalyst state that dictates the overall catalytic
performance and rules of catalytic behaviors; however, identification and stabilization of the …

Asymmetric Coordination of Single‐Atom Co Sites Achieves Efficient Dehydrogenation Catalysis

H Liu, Q Lei, R Miao, M Sun, C Qin… - Advanced Functional …, 2022 - Wiley Online Library
Tuning asymmetric coordination of metal single‐atom (SA) sites can provide a new
opportunity for optimizing the electronic structure of catalysts to achieve efficient catalysis …

Selective Conversion of Carbon Dioxide into Liquid Hydrocarbons and Long-Chain α-Olefins over Fe-Amorphous AlOx Bifunctional Catalysts

MK Khan, P Butolia, H Jo, M Irshad, D Han… - Acs …, 2020 - ACS Publications
Considerable progress has been made in the conversion of carbon dioxide (CO2), which is
highly thermodynamically stable, into liquid hydrocarbons using metal oxide/zeolite …

Unveiling the Activity Origin of Iron Nitride as Catalytic Material for Efficient Hydrogenation of CO2 to C2+ Hydrocarbons

B Zhao, M Sun, F Chen, Y Shi, Y Yu, X Li… - Angewandte …, 2021 - Wiley Online Library
Developing efficient catalytic materials and unveiling the active species are significant for
selective hydrogenation of CO2 to C2+ hydrocarbons. Fe2N@ C nanoparticles were …

Dinitrogen Activation by Heteronuclear Metal Carbide Cluster Anions FeTaC2: A 5d Early and 3d Late Transition Metal Strategy

LH Mou, Y Li, ZY Li, QY Liu, H Chen… - Journal of the American …, 2021 - ACS Publications
Cleavage of the strong N≡ N bond has long been a great challenge for energy-efficient
dinitrogen (N2) fixation; thus a reasonable design of reactive species to activate N2 under …

Recent strategies for enhancing the catalytic activity of CO2 hydrogenation to formate/formic acid over Pd-based catalyst

P Verma, S Zhang, S Song, K Mori, Y Kuwahara… - Journal of CO2 …, 2021 - Elsevier
The “greenhouse effect” caused by presence of the large amounts of carbon dioxide (CO 2)
is becoming extremely serious for the environment. Therefore, it is crucial to advance the …

Boosting Mass Exchange between Pd/NC and MoC/NC Dual Junctions via Electron Exchange for Cascade CO2 Fixation

D Xu, X Lin, QY Li, SN Zhang, SY Xia… - Journal of the …, 2022 - ACS Publications
Merging existing catalysts together as a cascade catalyst may achieve “one-pot” synthesis of
complex but functional molecules by simplifying multistep reactions, which is the blueprint of …

Modified cellulose nanocrystals immobilized AuPd nanoalloy for formic acid dehydrogenation

J Shen, Y Liang, C Wang, Y Zhu - Chemical Engineering Journal, 2023 - Elsevier
Formic acid (FA) is regarded as a promising liquid organic hydrogen transporter. Herein,
carriers for immobilizing ultrafine AuPd nanoparticles with a size of approximately 2 nm were …