Aliphatic azides are a versatile class of compounds found in a variety of biologically active
pharmaceuticals. These compounds are also recognized as useful precursors for the …

The term “C–H functionalisation” incorporates C–H activation followed by its transformation.
In a single line, this can be defined as the conversion of carbon–hydrogen bonds into …

Iodine was first isolated from the ash of seaweed by the industrial chemist B. Courtois in
1811 and named by JL Gay Lussac in 1813. Its name derives from the Greek term “violet …

Cyclizations of N-Acyliminium Ions | Chemical Reviews ACS ACS Publications C&EN CAS
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The azido group is found in large numbers of natural products, drugs, biochemicals and
materials and to date, many elegant and useful methods for the synthesis of organic azides …

A manganese-catalyzed highly site-and enantioselective benzylic C–H azidation of
indolines has been described. The practical method is applicable for azidation of a tertiary …

Azidoiodinanes 2 and 4a, b can be prepared from the appropriate benziodoxoles 1 and 3a,
b and trimethylsilyl azide in the form of stable, crystalline compounds. A single-crystal X-ray …

Reactions that directly transform aliphatic C–H bonds into alkyl azides are noticeably lacking
in the repertoire of synthetic reactions, despite the importance of molecules containing C–N3 …

Chemical transformations induced by hypervalent iodine reagents - ScienceDirect Skip to main
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The efficient azidation of β-keto esters and silyl enol ethers using a benziodoxole-derived
azide transfer reagent is reported. The azidation of cyclic β-keto esters could be achieved in …