Defect Engineering on CeO2‐Based Catalysts for Heterogeneous Catalytic Applications

C Yang, Y Lu, L Zhang, Z Kong, T Yang, L Tao… - Small …, 2021 - Wiley Online Library
With abundant crystal defects, cerium oxide (CeO2), widely used in heterogeneous
catalysis, has attracted extensive attention. In recent years, researchers have investigated …

N-Heterocyclic Carbene-Stabilized Atomically Precise Metal Nanoclusters

EL Albright, TI Levchenko, VK Kulkarni… - Journal of the …, 2024 - ACS Publications
This perspective highlights advances in the preparation and understanding of metal
nanoclusters stabilized by organic ligands with a focus on N-heterocyclic carbenes (NHCs) …

[HTML][HTML] Stabilizing ultrasmall Au clusters for enhanced photoredox catalysis

B Weng, KQ Lu, Z Tang, HM Chen, YJ Xu - Nature communications, 2018 - nature.com
Recently, loading ligand-protected gold (Au) clusters as visible light photosensitizers onto
various supports for photoredox catalysis has attracted considerable attention. However, the …

Defect-Induced Band Gap Narrowed CeO2 Nanostructures for Visible Light Activities

MM Khan, SA Ansari, D Pradhan, DH Han… - Industrial & …, 2014 - ACS Publications
This work reports an electron beam irradiation (30 kGy and 90 kGy) approach to narrow the
band gap of the pristine CeO2 nanostructure (p-CeO2) to enhance their visible light activity …

Glutathione-capped gold nanoclusters as photosensitizers. Visible light-induced hydrogen generation in neutral water

YS Chen, PV Kamat - Journal of the American Chemical Society, 2014 - ACS Publications
Glutathione-capped metal nanoclusters (Au x-GSH NCs) which exhibit molecular-like
properties are employed as a photosensitizer for hydrogen generation in a …

Bridging Au nanoclusters with ultrathin LDH nanosheets via ligands for enhanced charge transfer in photocatalytic CO2 reduction

Y Bo, P Du, H Li, R Liu, C Wang, H Liu, D Liu… - Applied Catalysis B …, 2023 - Elsevier
Au nanoclusters (NCs) bring new opportunities for constructing visible-light photocatalysts
for solar-driven CO 2 conversion, whereas the agglomeration under illumination and lack of …

Copper Quantum Clusters in Protein Matrix: Potential Sensor of Pb2+ Ion

N Goswami, A Giri, MS Bootharaju, PL Xavier… - Analytical …, 2011 - ACS Publications
A one-pot synthesis of extremely stable, water-soluble Cu quantum clusters (QCs) capped
with a model protein, bovine serum albumin (BSA), is reported. From matrix-assisted laser …

Electron-beam induced synthesis of nanostructures: a review

IG Gonzalez-Martinez, A Bachmatiuk, V Bezugly… - Nanoscale, 2016 - pubs.rsc.org
As the success of nanostructures grows in modern society so does the importance of our
ability to control their synthesis in precise manners, often with atomic precision as this can …

Luminescent quantum clusters of gold in bulk by albumin‐induced core etching of nanoparticles: metal ion sensing, metal‐enhanced luminescence, and biolabeling

MA Habeeb Muhammed, PK Verma… - … A European Journal, 2010 - Wiley Online Library
The synthesis of a luminescent quantum cluster (QC) of gold with a quantum yield of∼ 4% is
reported. It was synthesized in gram quantities by the core etching of mercaptosuccinic acid …

New protocols for the synthesis of stable Ag and Au nanocluster molecules

T Udayabhaskararao, T Pradeep - The journal of physical …, 2013 - ACS Publications
“Catching” metals in the nonmetallic form in solution, as they grow to bulk, is one of the most
exciting areas of contemporary materials research. A new kind of stabilization to catch the …