Photocatalytic late-stage C–H functionalization
The emergence of modern photocatalysis, characterized by mildness and selectivity, has
significantly spurred innovative late-stage C–H functionalization approaches that make use …
significantly spurred innovative late-stage C–H functionalization approaches that make use …
Direct photocatalyzed hydrogen atom transfer (HAT) for aliphatic C–H bonds elaboration
Direct photocatalyzed hydrogen atom transfer (d-HAT) can be considered a method of
choice for the elaboration of aliphatic C–H bonds. In this manifold, a photocatalyst (PCHAT) …
choice for the elaboration of aliphatic C–H bonds. In this manifold, a photocatalyst (PCHAT) …
[HTML][HTML] Recent advances in visible light-activated radical coupling reactions triggered by (i) ruthenium,(ii) iridium and (iii) organic photoredox agents
Photoredox chemistry with organic or transition metal agents has been reviewed in earlier
years, but such is the pace of progress that we will overlap very little with earlier …
years, but such is the pace of progress that we will overlap very little with earlier …
A catalytic alkene insertion approach to bicyclo [2.1. 1] hexane bioisosteres
S Agasti, F Beltran, E Pye, N Kaltsoyannis… - Nature Chemistry, 2023 - nature.com
Abstract C (sp 3)-rich bicyclic hydrocarbon scaffolds, as exemplified by bicyclo [1.1. 1]
pentanes, play an increasingly high-profile role as saturated bioisosteres of benzenoids in …
pentanes, play an increasingly high-profile role as saturated bioisosteres of benzenoids in …
[HTML][HTML] Recent progress in cathodic reduction-enabled organic electrosynthesis: Trends, challenges, and opportunities
B Huang, Z Sun, G Sun - eScience, 2022 - Elsevier
Compared with general redox chemistry, electrochemistry using the electron as a potent,
controllable, yet traceless alternative to chemical oxidants/reductants usually offers more …
controllable, yet traceless alternative to chemical oxidants/reductants usually offers more …
Ketyl radical coupling enabled by polycyclic aromatic hydrocarbon electrophotocatalysts
JM Edgecomb, SN Alektiar, NGW Cowper… - Journal of the …, 2023 - ACS Publications
Herein, we report a new class of electrophotocatalysts, polycyclic aromatic hydrocarbons,
that promote the reduction of unactivated carbonyl compounds to generate versatile ketyl …
that promote the reduction of unactivated carbonyl compounds to generate versatile ketyl …
Enantioselective radical addition to ketones through Lewis acid-enabled photoredox catalysis
L Hou, Y Zhou, H Yu, T Zhan, W Cao… - Journal of the American …, 2022 - ACS Publications
Photocatalysis opens up a new window for carbonyl chemistry. Despite a multitude of
photochemical reactions of carbonyl compounds, visible light-induced catalytic asymmetric …
photochemical reactions of carbonyl compounds, visible light-induced catalytic asymmetric …
Ketone–olefin coupling of aliphatic and aromatic carbonyls catalyzed by excited-state acridine radicals
NJ Venditto, YS Liang, RK El Mokadem… - Journal of the …, 2022 - ACS Publications
Ketone–olefin coupling reactions are common methods for the formation of carbon–carbon
bonds. This reaction class typically requires stoichiometric or super stoichiometric quantities …
bonds. This reaction class typically requires stoichiometric or super stoichiometric quantities …
Catalysis with diboron (4)/pyridine: application to the broad-scope [3+ 2] cycloaddition of cyclopropanes and alkenes
Z Ding, Z Liu, Z Wang, T Yu, M Xu, J Wen… - Journal of the …, 2022 - ACS Publications
In contrast to the extensive but non-recyclable use of tetraalkoxydiboron (4) compounds as
stoichiometric reagents in diverse reactions, this article reports an atom-economical reaction …
stoichiometric reagents in diverse reactions, this article reports an atom-economical reaction …
Molecular Editing of Ketones through N-Heterocyclic Carbene and Photo Dual Catalysis
QZ Li, MH He, R Zeng, YY Lei, ZY Yu… - Journal of the …, 2024 - ACS Publications
The molecular editing of ketones represents an appealing strategy due to its ability to
maximize the structural diversity of ketone compounds in a straightforward manner …
maximize the structural diversity of ketone compounds in a straightforward manner …