The addition of X3Si–H or X2B–H (X= H, OR or R) across a C–C multiple bond is a well-
established method for incorporating silane or borane groups, respectively, into …

At the advent of cross-coupling chemistry, carbon electrophiles based on halides or
pseudohalides were the only suitable electrophilic coupling partners. Almost two decades …

Organosilicon compounds act as a nucleophile upon activation by an appropriate base and
behave in a manner similar to main-group organometallic reagents. In the last decades …

The “phenylpropenoids” are a well-known set of naturally occurring compounds obtained
mainly from plant sources. 1, 2 Of this group, the generalized 2-propenylbenzenes 1 and 1 …

1, 2-Disubstituted alkenes such as vinyl arenes, vinyl silanes, and vinyl boronates are
among the most versatile building blocks that can be found in every sector of chemical …

The first visible light‐induced Pd‐catalyzed Heck reaction of α‐heteroatom substituted alkyl
iodides and‐bromides with vinyl arenes/heteroarenes has been developed. This …

Palladium-catalyzed cross-coupling reactions have transformed the exploration of chemical
space in the search for materials, medicines, chemical probes, and other functional …

The aryl-substituted bis (imino) pyridine cobalt methyl complex,(MesPDI) CoCH3 (MesPDI=
2, 6-(2, 4, 6-Me3C6H2-N CMe) 2C5H3N), promotes the catalytic dehydrogenative …

Herein, we report a regioselective alkenyl electrophile synthesis from unactivated olefins
that is based on a direct and regioselective C− H thianthrenation reaction. The selectivity is …

Two new classes of highly active yet air-and moisture-stable π-R-allylpalladium complexes
containing bulky biaryl-and bipyrazolylphosphines with extremely broad ligand scope have …