Sustainability assessment of mechanochemistry by using the twelve principles of green chemistry

KJ Ardila‐Fierro, JG Hernández - ChemSusChem, 2021 - Wiley Online Library
In recent years, mechanochemistry has been growing into a widely accepted alternative for
chemical synthesis. In addition to their efficiency and practicality, mechanochemical …

Mechanochemistry: new tools to navigate the uncharted territory of “impossible” reactions

F Cuccu, L De Luca, F Delogu, E Colacino… - …, 2022 - Wiley Online Library
Mechanochemical transformations have made chemists enter unknown territories, forcing a
different chemistry perspective. While questioning or revisiting familiar concepts belonging …

Long‐Life Regenerated LiFePO4 from Spent Cathode by Elevating the d‐Band Center of Fe

K Jia, J Ma, J Wang, Z Liang, G Ji, Z Piao… - Advanced …, 2023 - Wiley Online Library
A large amount of spent LiFePO4 (LFP) has been produced in recent years because it is one
of the most widely used cathode materials for electric vehicles. The traditional …

Mechanochemical synthesis of metal oxide nanoparticles

T Tsuzuki - Communications Chemistry, 2021 - nature.com
In the last decades, mechanochemical processing has emerged as a sustainable method for
the large-scale production of a variety of nanomaterials. In particular, mechanochemical …

Mechanochemically generated calcium‐based heavy Grignard reagents and their application to carbon–carbon bond‐forming reactions

P Gao, J Jiang, S Maeda, K Kubota… - Angewandte Chemie, 2022 - Wiley Online Library
In sharp contrast to the use of conventional magnesium‐based Grignard reagents (R− MgX),
the application of calcium‐based heavy Grignard reagents (R− CaX) in organic synthesis …

Mechanochemical synthesis of inverse vulcanized polymers

P Yan, W Zhao, F McBride, D Cai, J Dale… - Nature …, 2022 - nature.com
Inverse vulcanization, a sustainable platform, can transform sulfur, an industrial by-product,
into polymers with broad promising applications such as heavy metal capture …

Salient achievements in synthetic organic chemistry enabled by mechanochemical activation

E Juaristi, CG Avila-Ortiz - Synthesis, 2023 - thieme-connect.com
Although known for millennia, it is only recently that mechanochemistry has received serious
attention by chemists. Indeed, during the past 15 years an extraordinary number of reports …

Mechanochemical Grignard Reactions with Gaseous CO2 and Sodium Methyl Carbonate**

VS Pfennig, RC Villella, J Nikodemus… - Angewandte …, 2022 - Wiley Online Library
A one‐pot, three‐step protocol for the preparation of Grignard reagents from
organobromides in a ball mill and their subsequent reactions with gaseous carbon dioxide …

Ball milling treatment of Mn3O4 regulates electron transfer pathway for peroxymonosulfate activation

H Liu, X Dai, L Kong, C Sui, Z Nie, Y Liu, B Cai… - Chemical Engineering …, 2023 - Elsevier
Heterogeneous metal catalysts have attracted considerable interest in advanced oxidation
processes (AOPs) for wastewater treatment by activating peroxymonosulfate (PMS) …

Tinkering with mechanochemical tools for scale up

JF Reynes, V Isoni, F García - … Chemie International Edition, 2023 - Wiley Online Library
Mechanochemistry provides an environmentally benign platform to develop more
sustainable chemical processes by limiting raw materials, energy use, and waste generation …