Supramolecular organization in confined nanospaces

G Tabacchi - ChemPhysChem, 2018 - Wiley Online Library
Empty spaces are abhorred by nature, which immediately rushes in to fill the void. Humans
have learnt pretty well how to make ordered empty nanocontainers, and to get useful …

The effect of pressure on open-framework silicates: elastic behaviour and crystal–fluid interaction

GD Gatta, P Lotti, G Tabacchi - Physics and Chemistry of Minerals, 2018 - Springer
The elastic behaviour and the structural evolution of microporous materials compressed
hydrostatically in a pressure-transmitting fluid are drastically affected by the potential crystal …

High-pressure single-crystal structures of 3D lead-halide hybrid perovskites and pressure effects on their electronic and optical properties

A Jaffe, Y Lin, CM Beavers, J Voss, WL Mao… - ACS central …, 2016 - ACS Publications
We report the first high-pressure single-crystal structures of hybrid perovskites. The
crystalline semiconductors (MA) PbX3 (MA= CH3NH3+, X= Br–or I–) afford us the rare …

Linearly polymerized benzene arrays as intermediates, tracing pathways to carbon nanothreads

B Chen, R Hoffmann, NW Ashcroft… - Journal of the …, 2015 - ACS Publications
How might fully saturated benzene polymers of composition [(CH) 6] n form under high
pressure? In the first approach to answering this question, we examine the stepwise …

[HTML][HTML] One-dimensional diamondoid polyaniline-like nanothreads from compressed crystal aniline

MM Nobrega, E Teixeira-Neto, AB Cairns… - Chemical …, 2018 - pubs.rsc.org
Low-dimensional nanomaterials such as highly ordered polyaniline (PANI) have attracted
considerable interest due to their expected extraordinary electronic and optoelectronic …

Unraveling the Molecular Structure of Zeolite–Octyl Methoxycinnamate Hybrid UV Filters: A Combined Spectroscopic and Computational Approach

M Fischer, R Fantini, R Arletti, J Brauer… - The Journal of Physical …, 2023 - ACS Publications
In this contribution, we tried to shed light on the molecular structure of octyl
methoxycinnamate (octinoxate, OMC) adsorbed in NaX zeolite, which represents a …

Confined synthesis of conjugated microporous polymers for selective photocatalytic oxidation of amines

S You, Z Ding, R Yuan, J Long, C Xu - Journal of Colloid and Interface …, 2024 - Elsevier
Photocatalytic oxidative coupling of amines is considered a mild, efficient, and sustainable
strategy for the synthesis of imines. As a versatile organic semiconductor, conjugated …

Synthesis of 1D polymer/zeolite nanocomposites under high pressure

M Santoro, D Scelta, K Dziubek, M Ceppatelli… - Chemistry of …, 2016 - ACS Publications
Recently, simple carbon based polymers have been synthesized at high pressures in
silicalite, a pure SiO2 zeolite with a 3D system of mutually interconnected microchannels …

Tuning Negative Thermal Expansion in AlPO4-17 by Insertion of Guest Molecules

F Alabarse, B Baptiste, B Joseph… - The Journal of Physical …, 2022 - ACS Publications
The very strong negative thermal expansion in the porous aluminophosphate AlPO4-17 with
a hexagonal erionite structure was tuned by the insertion of oxygen molecules at high …

Opportunities and challenges for polymer science using synchrotron-based infrared spectroscopy

GJ Ellis, MC Martin - European Polymer Journal, 2016 - Elsevier
Many breakthrough advances that are often at the cutting edge of technological
development take place at synchrotron facilities. In the case of IR spectroscopy, the last …