Five-Coordinate Complex [RuHCl(CO)(PPri3)2] as a Precursor for the Preparation of New Cyclopentadienylruthenium Compounds Containing Unsaturated η1 …
MA Esteruelas, AV Gómez, FJ Lahoz, AM López… - …, 1996 - ACS Publications
The five-coordinate complex [RuHCl (CO)(PPri3) 2](1) reacts with cyclopentadiene in
methanol under reflux to give [RuH (η5-C5H5)(CO)(PPri3)](2) and [HPPri3] Cl. The …
methanol under reflux to give [RuH (η5-C5H5)(CO)(PPri3)](2) and [HPPri3] Cl. The …
Synthesis and derivatization of the 2-amino-closo-decaborate anion [2-B10H9NH3]−
IB Sivaev, AV Natal'ya, VI Bragin, ZA Starikova… - Journal of …, 2002 - Elsevier
A novel high-yield method of synthesis of the [2-B10H9NH3]− anion was elaborated. The
method proposed includes reaction of the closo-decaborate anion with acetonitrile in the …
method proposed includes reaction of the closo-decaborate anion with acetonitrile in the …
Displacement of phenyl and styryl ligands by benzophenone imine and 2-vinylpyridine on Ruthenium and Osmium
ML Buil, MA Esteruelas, E Goni, M Oliván… - Organometallics, 2006 - ACS Publications
The phenyl complexes MPhCl (CO)(PiPr3) 2 (M= Ru (3), Os (4)) have been prepared by
reaction of MHCl (CO)(PiPr3) 2 (M= Ru (1), Os (2)) with HgPh2. In solution the phenyl ligand …
reaction of MHCl (CO)(PiPr3) 2 (M= Ru (1), Os (2)) with HgPh2. In solution the phenyl ligand …
Δ2- and Δ3-Azaosmetine Complexes as Intermediates in the Stoichiometric Imination of Phenylacetylene with Oximes
R Castarlenas, MA Esteruelas, E Oñate - Organometallics, 2001 - ACS Publications
Complexes [Os {(E)-CH CHPh} Cl (N CR2)(PiPr3) 2][CF3SO3][CR2= CMe2 (1), C (CH2)
4CH2 (2)] react with carbon monoxide to give the Δ2-1, 2-azaosmetine derivatives [OsCl …
4CH2 (2)] react with carbon monoxide to give the Δ2-1, 2-azaosmetine derivatives [OsCl …
Reactivity of the Imine−Vinylidene Complexes OsCl2(CCHPh)(NHCR2)(PiPr3)2 [CR2 = CMe2, C(CH2)4CH2]
R Castarlenas, MA Esteruelas… - …, 2001 - ACS Publications
The reactivity of the imine− vinylidene compounds OsCl2 (C CHPh)(NH CR2)(PiPr3) 2
[CR2= CMe2 (1), C (CH2) 4CH2 (2)] toward amines, nBuLi, and HBF4 has been studied …
[CR2= CMe2 (1), C (CH2) 4CH2 (2)] toward amines, nBuLi, and HBF4 has been studied …
Ortho-CH Activation of Aromatic Ketones, Partially Fluorinated Aromatic Ketones, and Aromatic Imines by a Trihydride-Stannyl-Osmium(IV) Complex
MA Esteruelas, A Lledós, M Oliván, E Oñate… - …, 2003 - ACS Publications
Complex OsH3 (SnPh2Cl){η2-CH2 C (CH3) PiPr2}(PiPr3)(1) reacts with acetophenone and
benzophenone to give OsH2 (SnPh2Cl){C6H4C (O) R}(PiPr3) 2 (R= CH3 (2), Ph (3)). In the …
benzophenone to give OsH2 (SnPh2Cl){C6H4C (O) R}(PiPr3) 2 (R= CH3 (2), Ph (3)). In the …
Formation of Imine− Vinylidene− Osmium (II) Derivatives by Hydrogen Transfer from Alkenyl Ligands to Azavinylidene Groups in Alkenyl− Azavinylidene− Osmium (IV) …
R Castarlenas, MA Esteruelas, E Oñate - Organometallics, 2000 - ACS Publications
Treatment at room temperature of the hydride− azavinylidene complexes OsHCl2 (N
CR2)(PiPr3) 2 [CR2= CMe2 (1), C (CH2) 4CH2 (2)] with Ag [CF3SO3] and the subsequent …
CR2)(PiPr3) 2 [CR2= CMe2 (1), C (CH2) 4CH2 (2)] with Ag [CF3SO3] and the subsequent …
Hydrozirconierung von nitrilen: Die bildung ein-und zweikerniger (alkylidenamido) zirconocen-komplexe
W Frömberg, G Erker - Journal of organometallic chemistry, 1985 - Elsevier
Zusammenfassung Die Hydrozirconierung von Nitrilen liefert die Verbindungen Cp 2 Zr (-
N CHR) Cl (9a–9c)(R= CH 3, C 6 H 5, CH 2 Ph). Anschliessende Umsetzung mit einem …
N CHR) Cl (9a–9c)(R= CH 3, C 6 H 5, CH 2 Ph). Anschliessende Umsetzung mit einem …
The Structure of 2‐Azaallenium Cations
M Al‐Talib, I Jibril, EU Würthwein… - Chemische …, 1984 - Wiley Online Library
According to an X‐ray structural analysis, the 2‐azaallenium hexachloroantimonate 23
crystallizes with the topology of an allene (geometry 1a) and not of a 2‐azaallyl cation (1b) …
crystallizes with the topology of an allene (geometry 1a) and not of a 2‐azaallyl cation (1b) …
Formation of azabutadienyl fragments by addition of the isopropenyl substituent of a phosphine to benzonitriles, promoted by an osmium center
M Baya, MA Esteruelas, AI González, AM López… - …, 2005 - ACS Publications
Complex Os (η5-C5H5) Cl {[η2-CH2 C (CH3)] PiPr2}(1) reacts with p-tolunitrile, benzonitrile,
and p-chlorobenzonitrile to give the corresponding iminophosphine derivatives Os (η5 …
and p-chlorobenzonitrile to give the corresponding iminophosphine derivatives Os (η5 …